从档案馆:使用质谱技术对皇家密封带进行化学研究
Barbara Wagner1, Anna Czajka2, Katarzyna Lech3
1University of Warsaw: Uniwersytet Warszawski, Faculty of Chemistry, Zwirki i Wigury 101, 02-089, Warsaw, POLAND.
ChemPlusChem
|May 21, 2025
概括
对1506 Łaski 的化学分析.
科学领域:
- 材料科学 材料科学 材料科学
- 分析化学 分析化学
- 艺术保护 艺术保护
背景情况:
- 作为联合国教科文组织世界记忆名录项目,拉斯基的规约 (1506年) 绳索表现出与年龄相关的显著恶化.
- 了解这些历史性绳索的化学成分对于有效的保护至关重要.
- 之前对类似的皇室文档线索的分析强调了需要详细的材料特征的需要.
研究的目的:
- 确定在拉斯基章程和其他当代皇家文件的密封绳中使用的无机 mordants 和有机染料.
- 为了将化学成分与的观察到的恶化模式相关联.
- 为这些宝贵的历史文物提供数据,以便为这些宝贵的历史文物制定明智的保护策略.
主要方法:
- 激光切除感应合等离子体质谱法 (LA-ICP-MS) 用于无机元素分析.
- 高性能液体染色学与UV-Vis和电子喷射电离双重质谱学 (HPLC-UV-Vis-ESI MS/MS) 结合使用,用于有机染料的识别.
- 现场元素分析使用巴托芬林 (Bphen) 浸泡纸.
主要成果:
- 在黑色的绳索中发现了ellagitannin染料;在一个红色的绳索中发现了madder和lac染料标记.
- 可溶性红木 (可能是pernambuco/brazilwood),有时与接混合,在其他红色绳索中检测到.
- 拉斯基法规的黑色和红色绳索中铁的优势与降解相关;白色绳索中硫含量更高.
结论:
- 化学成分,特别是铁剂的存在,显著影响历史绳索的保存状态.
- 识别特定的染料和剂为了解降解机制提供了基础.
- 这些发现对于制定有针对性的保护和恢复协议来减轻进一步的损害至关重要.
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