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相关概念视频

Intermolecular Forces03:13

Intermolecular Forces

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Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
61.4K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

15.1K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
15.1K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

64.2K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
64.2K
Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

34.9K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
34.9K
Formation of Complex Ions03:45

Formation of Complex Ions

24.0K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
24.0K
Radical Formation: Homolysis00:54

Radical Formation: Homolysis

3.7K
A bond is formed between two atoms by sharing two electrons. When this bond is broken by supplying sufficient energy, either two electrons can be taken up by one atom forming ions by the cleavage called heterolysis, or the two electrons are shared by two atoms, with one each creating radicals by the cleavage called homolysis.
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Updated: Sep 20, 2025

A Microfluidic Approach for the Study of Ice and Clathrate Hydrate Crystallization
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A Microfluidic Approach for the Study of Ice and Clathrate Hydrate Crystallization

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通过高离子导电性实现直接冰分裂为H2和O2

Bohan Deng1,2, Guangqiang Yu3, Wei Zhao1

  • 1State Key Laboratory of New Ceramic Materials, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China.

Journal of the American Chemical Society
|May 23, 2025
PubMed
概括
此摘要是机器生成的。

研究人员在低至-40°C的温度下成功地将固态冰分解成和氧气. 这一突破利用冰作为固体电解质,

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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
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An Externally-Heated Diamond Anvil Cell for Synthesis and Single-Crystal Elasticity Determination of Ice-VII at High Pressure-Temperature Conditions
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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
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科学领域:

  • 电化学
  • 材料科学
  • 能量储存

背景情况:

  • H2O (水) 的分子分解对于能量转化和储存至关重要.
  • 虽然液态水分离已经确立,但固态冰的分解仍然是一个挑战.

研究的目的:

  • 在零度以下的温度下,
  • 研究冰作为电化学应用的固体电解质.
  • 探索使用冰的新能源转换和储存方式.

主要方法:

  • 固态冰的电化学分析.
  • 在冰中测量质子和氧化导电.
  • 用于分裂冰的电压和电流密度测量.
  • 在零度以下的温度下进行能效计算.

主要成果:

  • 在低至-40°C的温度下成功地直接分裂冰.
  • 冰作为一种高性能固体电解质,用于质子和氧化的导电.
  • 冰中的质子流动性比液态水高1-2个数量级.
  • 在2.18V下实现冰裂,在-10°C下达到70%的能效.
  • 绕过液态水分的交叉问题.

结论:

  • 冰可以在零度以下的温度下直接电化学分裂, 开辟新的能量转化途径.
  • 冰是有效的固体电解质,在质子流动性方面表现优于液体水,避免交叉.
  • 这些发现为冰中的电化学过程提供了新的见解,并为低温储能解决方案提供了机会.