使用酸和多德乙醇对酸海绵表面进行修改,以从水中分离柴油油泄漏
Ronald Wijaya1, Kuan-Chen Cheng2, Shella Permatasari Santoso3
1Chemical Engineering Department, National Taiwan University of Science and Technology, Taipei 10607, Taiwan.
International journal of biological macromolecules
|May 24, 2025
概括
环保的阿尔金酸盐海绵被改进为柴油泄漏清理,使用酸和多德乙醇. 修改后的海绵具有很高的吸收能力和耐用性,为石油整治提供了可持续的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 聚合物化学 聚合物化学
背景情况:
- 柴油泄漏对环境构成重大威胁,需要有效和环保的补救策略.
- 传统的吸油剂往往缺乏效率,耐用性或带来次要的环境风险.
研究的目的:
- 开发一个环保和高效的吸收海绵,用于柴油泄漏补救.
- 通过表面修饰来提高基于酸盐的海绵的性能.
主要方法:
- 酸聚合物交叉连接,然后用酸和多德乙醇 (TA/Do) 进行表面修饰.
- 优化交叉连接的持续时间以平衡吸收和结构完整性.
- 使用FTIR,XPS和水接触角度测量进行表征.
- 评估吸收能力,吸收-脱吸周期和动力建模.
主要成果:
- 最佳酸盐海绵 (AA-3-TA/Do) 显示柴油吸收能力为17.54g/g,比未修改的海绵增加36%.
- 表面的修改赋予了显著的疏水性 (水接触角度为120.2°).
- 经过修改后的海绵在34个循环后保留了大约90%的吸收能力,并显示出快速的柴油吸收动力学.
- 细胞毒性测定证实了开发的吸附剂的无毒性.
结论:
- 使用可访问材料的简单,可扩展的表面修改策略显著提高了用于柴油整治的酸盐海绵性能.
- 修改TA/Do的酸海绵为清理油污提供了一个有希望的,生态兼容的,可重复使用的解决方案.
- 这种方法避免了复杂的技术和危险的试剂,促进了可持续的环境管理.
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