驳斥"X射线衍射的新理论" - - 一种反向空间方法.
Elias Vlieg1, Paul Tinnemans1, René de Gelder1
1Radboud University, Institute for Molecules and Materials, Heyendaalseweg 135, Nijmegen, 6525AJ, The Netherlands.
概括
费斯特关于X射线衍射的新理论是不正确的. 分析显示路径长度计算中的概念错误,而不是新的散射现象.
科学领域:
- 晶体学 晶体学是指结晶学.
- 材料科学 材料科学 材料科学
- 物理 物理学 物理
背景情况:
- 提出了一种新的X射线衍射理论,以解释从少数晶体样本中获得完整的粉末图案.
- 这个理论声称在布拉格角度检测到额外的强度,这表明了一种新的X射线散射方法.
研究的目的:
- 批判性地重新评估Fewster提出的X射线衍射理论.
- 通过使用传统的散射原理,识别和澄清拟议理论中的概念错误.
主要方法:
- 使用传统的散射理论对X射线衍射的分析.
- 分散现象的相互空间描述.
- 检查路径长度计算和残余强度效应.
主要成果:
- 费斯特的理论包含在路径长度计算中的概念错误,导致偏离传统理论.
- 来自晶体终结的残余强度对典型的粉末衍射模式的影响最小.
结论:
- 提出的理论并不代表X射线散射的新方法.
- 观察到的效应归因于计算错误,而不是新的现象.
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