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Updated: Sep 20, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
06:35

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

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所有N-异环碳素受保护的超原子Ag8集群

Li-Ying Sun1, Fang Wang1, Yuan Shui2

  • 1Key State Laboratory of Natural Functional Molecule Chemistry of the Ministry of Education, Xi'an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Material Science, Northwest University, Xi'an, 710127, P.R. China.

Angewandte Chemie (International ed. in English)
|May 27, 2025
PubMed
概括

研究人员合成了第一个全N-异环碳 (NHC) 保护的超原子银集群. 这个Ag8星团由于银环和NHC连接体之间强大的静电吸引力而表现出独特的特性,为新的应用铺平了道路.

关键词:
原子精度集群原子精度集群N - 异环碳酸 N - 异环碳酸银 (((I) 碳化合物银子 (I) 集群

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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