/异型兴奋剂使P2型-基离子电池能够长期循环
Xu Wang1, Zixiang Yang1, Mikhail Pugach2
1State Key Laboratory of Silicon and Advanced Semiconductor Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310058, China.
Small methods
|May 30, 2025
概括
用铜和进行二进制兴奋剂可以增强P2-Na0.67Ni0.33Mn0.67O2用于离子电池的阴极材料. 这种修改稳定了结构,使高能量密度和卓越的循环稳定性用于先进的电池应用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 由于高的理论能量密度,P2-Na0.67Ni0.33Mn0.67O2显示出对离子电池的承诺.
- 挑战包括P2-O2相位过渡,Jahn-Teller扭曲和Na+/空位排序,限制性能.
研究的目的:
- 使用Cu/Li二元兴奋剂稳定P2-Na0.67Ni0.33Mn0.67O2结构.
- 为了提高电化学性能和离子电池阴极的循环稳定性.
主要方法:
- 引入Li到金属部位和Cu到P2-Na0.67Ni0.33Mn0.67O2的过渡金属部位.
- 使用修改过的阴极和硬碳阳极制造的全细胞器件.
主要成果:
- 双部位兴奋剂抑制了相位过渡,改善了结构稳定性.
- 在全细胞设备中实现了379.3Wh kg-1的高能量密度.
- 证明了出色的循环稳定性,在1C的200个循环中保持了84%的容量,在10C的1000个循环中保持了71%的容量.
结论:
- /二元兴奋剂是一种有效的策略,用于增强离子电池的P2阴极材料.
- 修改后的阴极为开发高性能和稳定的离子储能系统提供了一个有前途的途径.
相关概念视频
Batteries and Fuel Cells
30.8K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.8K
Ions as Acids and Bases
26.2K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
26.2K
Common Ion Effect
46.0K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Châtelier’s principle. Consider the dissolution of silver iodide:
46.0K
Precipitation of Ions
30.0K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
30.0K
Formation of Complex Ions
25.8K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
25.8K
Long-term Depression
33.2K
Long-term depression, or LTD, is one of the ways by which synaptic plasticity—changes in the strength of chemical synapses—can occur in the brain. LTD is the process of synaptic weakening that occurs over time between pre and postsynaptic neuronal connections. The synaptic weakening of LTD works in opposition to synaptic strengthening by long-term potentiation (LTP) and together are the main mechanisms that underlie learning and memory.
33.2K


