Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

1.9K
The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
1.9K
Newman Projections02:06

Newman Projections

17.8K
Different notations are used to represent the three-dimensional structure of molecules on two-dimensional surfaces. One of the most commonly used representations is the dash-wedge formula. The dashed wedges, solid wedges, and the plane lines indicate the groups situated behind the plane, coming out of the plane, and in the plane, respectively.
The organic molecules rotate across the single bonds leading to numerous temporary three-dimensional structures of varying energy known as...
17.8K
[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement01:21

[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement

2.9K
The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
2.9K
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration02:34

Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration

8.7K
The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can significantly influence the rate.
8.7K
Hydrogen Bonds00:26

Hydrogen Bonds

126.3K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
126.3K
Fischer Projections02:18

Fischer Projections

14.0K
Learning to draw Fischer projections of molecules and understanding their relevance plays a crucial role in the visual depiction of organic molecules. A Fischer projection is a two-dimensional projection on a planar surface to simplify the three-dimensional wedge–dash representation of molecules. This is especially helpful in the case of molecules with multiple chiral centers that can be difficult to draw. Here, all the bonds of interest are represented as horizontal or vertical lines.
14.0K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Encapsulation of Cyclam Inside a Covalent Organic Framework for Efficient CO<sub>2</sub> and SO<sub>2</sub> Removal.

ACS applied materials & interfaces·2026
Same author

Recent Advances in Porous Hydrogen-Bonded Organic Frameworks for Luminescent and Photoelectric Sensing.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same author

Lanthanide-Anchored Hydrogen-Bonded Organic Frameworks for Luminescent Sensing.

ACS applied materials & interfaces·2026
Same author

Band-Gap Engineering of Isoreticular Hydrogen-Bonded Organic Frameworks for Boosting Photocatalytic Hydrogen Evolution.

Angewandte Chemie (International ed. in English)·2026
Same author

Enzyme-Inspired Hydrogen-Bonded Organic Frameworks for Synergistic Capture, Detection, and Degradation of Nerve Agent Simulants.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)·2025
Same author

Amino-Functionalized Lanthanide Metal-Organic Frameworks for Ratiometric Detection of Perfluorooctanoic Acid.

ACS applied materials & interfaces·2025

相关实验视频

Updated: Sep 19, 2025

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
09:33

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch

Published on: February 7, 2022

3.5K

在二维和三维结有机框架之间进行解决方案介导的光可逆开关.

Xiao Liu1, Yingxiang Ye2, Xu He1

  • 1School of Chemical Engineering and Technology, Hebei University of Technology, XiPing Dao 5340, Beichen District, Tianjin, 300401, P.R. China.

Angewandte Chemie (International ed. in English)
|May 31, 2025
PubMed
概括

研究人员开发了一种新型的光响应材料,可以使用光可逆地在3D和2D结构之间切换. 这种由光引起的转变使得可调节的特性和在防伪方面的潜在应用成为可能.

关键词:
配置转换转换的转换.通过结合的有机框架.兰化物 兰化物发光的阴影是什么意思照片交换机的照片交换机

更多相关视频

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
06:24

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal

Published on: October 31, 2019

6.5K
A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles
12:51

A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles

Published on: November 14, 2015

10.0K

相关实验视频

Last Updated: Sep 19, 2025

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
09:33

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch

Published on: February 7, 2022

3.5K
High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
06:24

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal

Published on: October 31, 2019

6.5K
A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles
12:51

A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles

Published on: November 14, 2015

10.0K

科学领域:

  • 材料科学 材料科学 材料科学
  • 超分子化学 超分子化学
  • 晶体学 晶体学是指结晶学.

背景情况:

  • 光敏晶体多孔材料通过光诱导的结构变化提供可调节的特性.
  • 在这些材料中实现可逆拓变换仍然是一个重大挑战.

研究的目的:

  • 开发一种具有光驱可逆结构转变的新型光响应材料.
  • 探索这种材料在防伪等应用中的潜力.

主要方法:

  • 使用光色二乙烯 (DAE) 和四氧化 (TAM) 的3D结有机框架 (HOF) 的自组装.
  • 用充电辅助的键来构建框架.
  • 采用交替的紫外线和可见光照射来控制DAE光异构化,并通过溶液介导过程诱导可逆的3D-2D结构切换.
  • 结合兰化物复合物来研究光色光共振能量转移 (FRET).

主要成果:

  • 一个3D结有机框架 (HOF-OF) 已成功合成.
  • 在3D和2DHOF结构之间实现可逆切换,通过光控制的DAE光异构化和溶液介导再结晶.
  • 该材料通过DAE光异构化控制的FRET在兰化物和DAE部分之间展示了可逆发光的开/关开关.

结论:

  • 开发的HOF-OF展示了3D和2D状态之间的光驱动可逆结构转换.
  • 该材料显示出智能防伪应用的潜力,因为它具有可逆发光切换.