一个基于亚的液态分子太阳能热 (MOST) 存储系统-能量载体和溶剂
Dominic Schatz1,2, Conrad Averdunk1,2, Rouven Fritzius1,2
1Institute of Organic Chemistry, Justus Liebig University Giessen, Heinrich-Buff-Ring 17, 35392, Gießen, Germany.
Small (Weinheim an der Bergstrasse, Germany)
|June 3, 2025
概括
一种新型的液态亚博烯能够有效地捕获和释放太阳能. 这种分子太阳能热系统提供高存储密度,可以作为功能溶剂,用于增强能源应用.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 可再生能源可再生能源是可再生能源.
背景情况:
- 分子太阳能热 (MOST) 系统通过光异构化储存太阳能,以后作为热释放.
- 液态亚 (AB) 已被用于大多数应用,但往往需要特殊条件才能有效运行.
研究的目的:
- 为大多数应用引入一种新型,低粘度,绿色光活性的2,6-二亚二.
- 展示其作为一个整洁的化合物和作为最活跃的溶剂的潜力.
主要方法:
- 2,6-difluoroazobenzene的连续流合成和光异构化.
- 储存密度和光响应性质的表征.
- 作为电解质和其他MOST材料 (例如,norbornadiene) 的溶剂的探索.
主要成果:
- 达到高储存密度 (218 kJ kg-1对于 (Z) - 异构体,137 kJ kg-1在绿光照射后),超过其他液态亚.
- 证明了高效的处理,送和整洁的处理.
- 展示了其作为MOST活性溶剂的实用性,诱导电解质中的导电性,用于电子催化逆异构化和与norbornadiene共同储存能量.
结论:
- 2,6-二亚烯是高效分子太阳能热能存储的非常有前途的候选物.
- 它作为液态亚博和MOST活性溶剂的独特特性为储能技术开辟了新的途径.
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