垂直交换在城市光化学污染边界层中的关键作用
Ying Shen1, Yinghong Wang2, Mengtian Cheng2
1State Key Laboratory of Atmospheric Environment and Extreme Meteorology, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China; University of Chinese Academy of Sciences, Beijing 100049, China.
The Science of the total environment
|June 4, 2025
概括
夜间的残余层运输对表面臭氧污染作出了重大贡献. 白天的垂直混合也通过加速光化学反应来增强臭氧,突显了减少氧化物排放的必要性.
科学领域:
- 大气化学 大气化学
- 边界层 气象学 边界层
- 空气污染的动力学
背景情况:
- 大气边界层 (ABL) 的臭氧动态与自由热带层不同,受到垂直交换过程的严重影响.
- 主要尚未解决的问题包括夜间残余层对表面臭氧的影响以及白天垂直混合在臭氧形成中的作用.
- 了解这些过程对于有效的空气质量管理和臭氧污染控制至关重要.
研究的目的:
- 审查ABL内垂直测量气象因素和污染物的观测方法.
- 分析ABL动态对臭氧及其前体的影响.
- 综合当前关于残余层运输和白天垂直混合对表面臭氧的贡献的知识.
主要方法:
- 对大气变量垂直分析的观测技术的审查.
- 关于边界层臭氧动态和前体度的已发表研究分析.
- 综合了关于残余层运输和自由对流效应的数据.
主要成果:
- 剩余层运输对表面臭氧水平的贡献为20-50%.
- 白天的自由对流通过增强垂直混合和光化学反应,加剧了表面臭氧.
- 氧化 (NOx) 在光化学污染中起着至关重要的作用.
结论:
- 在ABL内的垂直运输是臭氧污染的关键因素.
- 减少工业高氧化物排放可以有效地减轻空中臭氧的形成和向下传输.
- 为了降低表面臭氧度,需要采取更积极的NOx减排措施.
相关概念视频
Boundary Layer Characteristics
59
When a fluid encounters a solid surface, a boundary layer forms due to the interaction between the fluid's motion and the stationary surface. This phenomenon is characterized by a thin region adjacent to the surface where viscous forces dominate, influencing the fluid's velocity profile. The development of the boundary layer begins at the leading edge of the surface and evolves as the fluid moves downstream.As the fluid flows over the surface, friction between the fluid and the wall slows down...
59
External and Internal Respiration
3.7K
External respiration occurs in the lungs, and it is the first step in the journey of oxygen inside the body. When we inhale, oxygen enters our lungs and diffuses across the thin alveolar membrane. The alveoli are tiny, air-filled sacs that provide a vast surface area for gas exchange. Oxygen in the alveoli has a higher partial pressure (105 mmHg) than in the adjacent pulmonary capillaries (40 mmHg), establishing a pressure gradient. As a result, oxygen molecules move from the alveoli into the...
3.7K
Gas Exchange and Transport
69.7K
Gas exchange, the intake of molecular oxygen (O2) from the environment and the outflow of carbon dioxide (CO2) into the environment, is necessary for cellular function. Gas exchange during respiration occurs largely via the movement of gas molecules along pressure gradients. Gas travels from areas of higher partial pressure to areas of lower partial pressure. In mammals, gas exchange occurs in the alveoli of the lungs, which are adjacent to capillaries and share a membrane with them.
69.7K
Diffusion on Chromatography Columns
498
In column chromatography, when an analyte is introduced as a narrow band at the top of the column, the solutes begin to separate and broaden, developing a Gaussian profile. This broadening occurs due to various factors, such as longitudinal diffusion.
Longitudinal diffusion occurs when the solute molecules in the mobile phase diffuse from the more concentrated center of the chromatographic band to the more dilute regions on either side, both towards and against the flow direction. This...
Longitudinal diffusion occurs when the solute molecules in the mobile phase diffuse from the more concentrated center of the chromatographic band to the more dilute regions on either side, both towards and against the flow direction. This...
498
Lift
77
Lift is a fundamental aerodynamic force that acts perpendicular to the direction of airflow. It plays a central role in achieving and sustaining flight and in stabilizing various vehicles. Lift primarily originates from pressure differences created across surfaces, such as an airfoil. A lower pressure region forms above the wing, while a higher pressure region forms below it, generating an upward force. This differential results from the shape and orientation of the airfoil, enabling the wing...
77
The Sulfur Cycle
43.9K
Sulfur, an important element in the chemical makeup of proteins, is recycled through the atmosphere and aquatic and terrestrial environments. Found in the atmosphere as sulfur dioxide (SO2), sulfur is released by decaying organisms, weathered rocks, geothermal vents, volcanos, and burning fossil fuels. It is deposited into the ecosystem, cycled through the biotic community, and either released back into the atmosphere as gas or deposited in marine sediment for long-term storage and eventual...
43.9K


