在拉伸下,非定向的P(3HB) 和P(3HB-co-3HH) 之间的等级结构变化的差异
Masato Arakawa1, Taizo Kabe2, Tadahisa Iwata2
1Institute for Chemical Research Kyoto University Gokasho Uji Kyoto611-0011 Japan.
概括
将3 - 基酸 (3HH) 引入到多基酸中 (P3HB) 减少了脆性. 这项研究揭示了3HH在拉伸过程中如何改变P(3HB) 层次结构,从而改善实际应用的材料特性.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 生物材料是一种生物材料.
背景情况:
- 聚3-基酸盐 (P3HB) 是一种环保的聚合物,由于易碎性,其实际用途有限.
- 与3-基酸 (3HH) 的共聚合是一种增强P(3HB) 灵活性的策略.
研究的目的:
- 在单轴拉伸过程中研究P(3HB) 和P(3HB-co-3HH) 的结构演变.
- 阐明3HH整合对P(3HB) 层次结构和变形机制的影响.
主要方法:
- 在现场采用超微角,小角和广角X射线散射 (USAXS,SAXS,WAXS).
- 单轴拉伸实验是在未定向的P(3HB) 和P(3HB-co-11mol%-3HH) 样本上进行的.
主要成果:
- 3HH的融入抑制了P的结晶和降低了P中的晶体厚度.
- 由于3HH的存在,P(3HB) 的晶体结构被破坏了稳定.
- 观察到拉伸诱导的密度波动和异质变形,由于应力分散,共聚合物的波动较小.
结论:
- 无形3HH单元的引入改变了P(3HB的纳米结构和层次组织.
- 与3HH的共聚化通过改变结晶行为和促进变形期间的应力分散来增强P(3HB) 延展性.
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