间歇性改性Rh纳米晶用于高效且耐CO的性氧化电催化
Jianchao Yue1, Chaoyi Yang1, Yu Zhang1
1College of Chemistry and Molecular Sciences, Wuhan University Wuhan Hubei 430072 P. R. China wluo@whu.edu.cn.
开发用于性氧化的无电催化剂至关重要. 将插入纳米晶体 (N-Rh/C) 中,产生双位点催化剂,这些催化剂对燃料电池具有高度活性和耐碳排放性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 开发用于氧化反应 (HOR) 的高效电催化剂对于推进阳离子交换膜燃料电池至关重要.
- 基于的催化剂面临着诸如成本和性介质中的CO中毒等挑战.
研究的目的:
- 在性条件下为氧化反应 (HOR) 制备新型无电催化剂.
- 为了增强离子交换膜燃料电池的电催化剂的活性和一氧化碳 (CO) 耐受性.
主要方法:
- 在碳支 (N-Rh/C) 上合成间的纳米晶体.
- 性HOR的催化剂性能的电化学表征.
- 在现场表面增强红外吸收光谱 (SEIRAS) 探测反应中间体.
- 密度函数理论 (DFT) 计算以了解反应机制.
主要成果:
- N-Rh/C纳米晶体对性HOR具有很高的活性和CO耐受性.
- 同时的缺电子和富电子的Rh位是由间隔形成的.
- 间歇性抑制了电子缺陷部位的CO吸附,增强了CO的抗性.
- 在电子丰富的位点上增强OH吸附促进了水网络的形成,并加速了HOR动力学.
结论:
- 在Rh纳米晶体中的介质是开发先进的无HOR电催化剂的有效策略.
- 涉及Rh修改电子特性的双位点机制是实现高性能和CO耐受性的关键.
- N-Rh/C催化剂在离子交换膜燃料电池中的实际应用具有显著的潜力.
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