层次结构的空心纤维膜,可有效,选择性和可扩展地从水中去除离子
1State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China.
Advanced materials (Deerfield Beach, Fla.)
|June 11, 2025
概括
一种新的空心纤维膜有效地从水中去除有毒的离子 (Hg2+). 这种稳定,可重复使用的膜为水生环境中大规模的整治提供了可持续的解决方案.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 离子 (Hg2+) 具有高度毒性和生物积累,对水生生态系统和人类健康构成重大风险.
- 硫化聚烯二 (SPAN) 纳米颗粒显示出由于与Hg2+的强烈相互作用,对吸附有希望.
- 传统的SPAN纳米粒子应用存在不良稳定性,分布不均和潜在的二次污染.
研究的目的:
- 开发一种稳定,可再生和高度选择性的去除材料.
- 为了克服传统的SPAN纳米粒子分散和涂层方法的局限性.
- 提出一种具有成本效益和可扩展的整治方法.
主要方法:
- 使用湿制造一个SPAN集成的空心纤维膜的制造.
- 膜的层次结构和孔隙结构的表征.
- 评估Hg2+吸附性能,选择性和再生效率.
主要成果:
- 与SPAN集成的空洞纤维膜显示出出色的Hg2+吸附能力和稳定性.
- 获得了98.31%的初始Hg2+去除效率.
- 在五个再生周期后,膜保持了高效率 (≈99.7%),并在可扩展设备中显示了90.94%的去除率.
结论:
- 开发的SPAN集成的空心纤维膜是一种高度有效和稳定的材料,用于整治.
- 湿制造提供了一种可扩展和可持续的方法来生产先进的去除膜.
- 这种方法为解决水中大规模污染提供了一种新的,具有成本效益的解决方案.
相关概念视频
Ion Exchange
563
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
563
Potentiometry: Membrane Electrodes
484
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
484
Ion-Exchange Chromatography
389
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
389
Extraction: Advanced Methods
431
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
431
Detergent Purification of Membrane Proteins
5.1K
Detergents are used to purify the integral proteins of the membrane. The hydrophobic portion of the detergent can replace membrane phospholipids while solubilizing the membrane proteins. When detergent monomers reach a specific concentration in a solution called critical micelle concentration (CMC), they form micelles. Above CMC, the concentration of the detergent monomers remains in equilibrium with the micelle. The number of detergent monomers present in the CMC varies for each detergent, and...
5.1K
Dialysis
610
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
610


