热电二进制的结构特征和最近的进步 二氧化碳化物
Yasong Wu1, Binjie Zhou1, Lu Liu1
1Materials Genome Institute, Shanghai Engineering Research Center for Integrated Circuits and Advanced Display Materials, Shanghai University, Shanghai 200444, China.
Research (Washington, D.C.)
|June 11, 2025
概括
基于二进制的基化物提供高效的热电转换由于低导热率. 本综述探讨了它们的结构特征和热电应用的优化策略.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 能源转换 能源转换
背景情况:
- 热电 (TE) 材料直接将热量转化为电力,这对于能量收集至关重要.
- 基于二进制的基化物 (In-X) 具有较低的导热性和有前途的 TE 特性.
- 像In4Se2.35这样的材料中的结构异性增强了TE性能.
研究的目的:
- 审查In-X材料的结构特征和最近的TE研究.
- 了解In-X化合物中的结构属性关系.
- 探索优化In-X材料中TE特性的策略.
主要方法:
- 分析晶体结构,电子带结构和声子分散.
- TE优化策略的分类和讨论:缺陷工程,晶体定向,纳米结构和粒径控制.
- 审查最近的进步在化,化和硫化物.
主要成果:
- 在X化合物中,它们在电子和振动特性方面表现出相似之处和差异.
- 非传统的键 (例如,In-In) 显著影响带结构和格子振动.
- 为了提高这些材料的TE性能,已经采用了各种工程策略.
结论:
- 基于二进制的基化物对 TE 应用有前途.
- 对结构调制和优化技术的进一步研究至关重要.
- 本综述为设计下一代TE材料提供了洞察力.
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