在一个半灵活的分子内马特中,同otropic-nematic接口和离谱的自相一致的场理论
1School of Physics and Astronomy, University of Minnesota, Minneapolis, MN 55455, USA. qing0006@umn.edu.
Soft matter
|June 11, 2025
概括
这项研究使用自相一致场理论模拟了半灵活的液晶分子. 它揭示了分子灵活性和可压缩性如何影响相位边界和拓缺陷,如分线.
科学领域:
- 软物质物理学 软物质物理学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 液晶表现出复杂的相位行为和拓缺陷.
- 了解分子配置对于材料设计至关重要.
研究的目的:
- 用自相一致场理论描述半柔性液晶分子的平衡配置.
- 为了研究同位素 - 阴性相边界和拓缺陷 (偏差).
主要方法:
- 模拟线虫原体作为具有Maier-Saupe类型相互作用和排除体积的类似虫的链.
- 免费能量的数值最小化以获得热力学场 (分子密度,阴性顺序参数).
主要成果:
- 分析了带有同源性和平面对齐的接口,以及围绕不一致的双轴性.
- 研究了可压缩性,相互作用强度和链条灵活性对配置的影响.
- 缺陷核心大小随着压缩能力的下降而减少,受内马特相互作用强度和链持续长度的影响.
结论:
- 系统的可压缩性显著影响缺陷核心大小,在不可压缩的极限中达到常数.
- 链的灵活性和阴性相互作用强度调节缺陷核心大小和分子顺序.
- 核心尺寸与刚性链条的链条轮长度相当,随着灵活性的增加而减少.
相关概念视频
Electrostatic Boundary Conditions
424
Consider an external electric field propagating through a homogeneous medium. When the electric field crosses the surface boundary of the medium, it undergoes a discontinuity. The electric field can be resolved into normal and tangential components. The amount by which the field changes at any boundary is given by the difference between the field components above and below the surface boundary.
The surface integral of an electric field is given by Gauss's law in integral form and is related to...
The surface integral of an electric field is given by Gauss's law in integral form and is related to...
424
Potential Due to a Polarized Object
370
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
370
Electrostatic Boundary Conditions in Dielectrics
1.1K
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's...
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's...
1.1K
Induced Electric Dipoles
4.2K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.2K
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
44.0K
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
44.0K
Magnetostatic Boundary Conditions
880
An electric field suffers a discontinuity at a surface charge. Similarly, a magnetic field is discontinuous at a surface current. The perpendicular component of a magnetic field is continuous across the interface of two magnetic mediums. In contrast, its parallel component, perpendicular to the current, is discontinuous by the amount equal to the product of the vacuum permeability and the surface current. Like the scalar potential in electrostatics, the vector potential is also continuous...
880


