介层对304/45不钢板微观结构和耐腐蚀性的影响
1College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China.
Materials (Basel, Switzerland)
|June 13, 2025
概括
基于的中间层 (NiP,NiCuP) 防止不钢板中的碳扩散和敏感化. NiCuP中间层显著提高了耐腐蚀性,形成了一个密集的被动膜.
科学领域:
- 材料科学 材料科学 材料科学
- 腐蚀工程 腐蚀工程
- 金工业是金工业的一个方面.
背景情况:
- 不钢板的高温制备导致碳钢的碳扩散.
- 碳扩散会导致在谷物边界 (450-850°C) 的碳化物沉,从而启动颗粒间敏感化,并降低耐腐蚀性.
研究的目的:
- 设计和评估用于阻断碳扩散的NiP和NiCuP层间合金.
- 研究这些介层对不钢外微结构和耐腐蚀性的影响.
主要方法:
- 光学显微镜和扫描电子显微镜 (SEM) 用于微观结构分析.
- 电化学试验用于评估耐腐蚀性.
- 分析颗粒间腐蚀易受性和坑洞潜力的分析.
主要成果:
- 不受保护的304/45标本显示严重的碳扩散和较差的耐腐蚀性.
- NiP和NiCuP中间层在不同程度上提高了耐腐蚀性.
- 304/NiCuP/45样本表现出色的性能:0.25%的颗粒间腐蚀易感性和0.336V的插孔潜力.
结论:
- 在不钢外中,NiCuP中间层有效地减轻碳扩散和颗粒间敏感性.
- 304/NiCuP/45复合材料表现出优越的耐腐蚀性,这是由于具有n型半导体特征的密度更高的被动薄膜.
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