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Updated: Jun 16, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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在热解条件下通过单个和双个质子转移开放西洛皮拉诺斯环

Jacopo Lupi1, Bernardo Ballotta2,3, Leandro Ayarde-Henríquez2,3

  • 1CNR-ICCOM, Consiglio Nazionale Delle Ricerche, Pisa, Italy.

Journal of computational chemistry
|June 13, 2025
PubMed
概括

研究人员在β-D-xylopyranose热解中发现了一种新的过渡状态 (TS),可能会在较低温度下影响非循环产物形成. 这一发现为碳水化合物分解途径提供了新的见解.

关键词:
发现了自动反应机制的发现.气相热化学 气相热化学半纤维素的部分多路径规范变量过渡状态理论 (MP-VTST)多结构扭矩方法 (MS-T)

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