一种由硬木树生产的寡合性lignin衍生紫外线吸收器的表征
Chen Qu1, Keigo Mikame2, Yasunori Ohashi2
1Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan.
ACS omega
|June 16, 2025
概括
来自硬木木的寡合性素分离物显示出显著的紫外线保护. 这些天然的紫外线吸收器,以增强的结合结构为特征,为各种应用提供了潜力.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 生物质的价值化 生物质的价值化
背景情况:
- 紫外线 (UV) 辐射会对人体皮肤和材料造成重大损害.
- 素衍生的聚合物显示出UV保护的希望,但它们复杂的结构限制了使用.
- 从可再生资源开发有效的紫外线吸收器至关重要.
研究的目的:
- 用CuO和微波加热来降解硬木木木质素.
- 为了隔离和表征寡合体素分数的紫外线保护性质.
- 为评估生物质衍生紫外线吸收器建立一个标准化的协议.
主要方法:
- 硬木通过CuO和微波加热而降解.
- 顺序的溶剂提取 (乙乙,乙酸,乙) 以获得素分数.
- 使用UV光谱,HSQC NMR和GPC进行表征.
主要成果:
- 孤立的乙烯酸乙和溶性素分离物,具有与技术素相比的紫外线吸收能力.
- 在HSQC NMR检测中,两种分量中都显示出结合结构的增加 (甲基化碳酸,α-,α,β-结合酸).
- 平均分子重量为940 (乙乙酸) 和1200 (乙).
结论:
- 寡合体素分数作为天然紫外线吸收剂具有很好的潜力.
- 增强的结合结构与增加的紫外线吸收度相关.
- 描述协议可以指导生物质衍生紫外线保护化合物的评估.
相关概念视频
UV–Vis Spectroscopy: Woodward–Fieser Rules
25.7K
UV–Visible absorption spectra of conjugated dienes arise from the lowest energy π → π* transitions. The light-absorbing part of the molecule is called the chromophore, and the substituents directly attached to the chromophore are called auxochromes. A strong correlation exists between the absorption maxima, λmax, and the structure of a conjugated π system. The Woodward–Fieser rules predict the value of λmax for a given...
25.7K
UV–Vis Spectroscopy of Conjugated Systems
7.4K
Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
One of the factors influencing λmax is the extent...
One of the factors influencing λmax is the extent...
7.4K
Wood Products
138
Wood products encompass a broad range of materials crafted from wood strands, veneers, lumber, and even waste wood-like shreds, designed for both structural and nonstructural purposes. Various specialized wood products have been developed to enhance strength, durability, and versatility in building applications.
Glue-laminated wood, often referred to as glulam, combines multiple smaller pieces of dimensional lumber using adhesives to form a single, larger piece. Cross-laminated timber consists...
Glue-laminated wood, often referred to as glulam, combines multiple smaller pieces of dimensional lumber using adhesives to form a single, larger piece. Cross-laminated timber consists...
138
Softwoods and Hardwoods
260
Softwoods and hardwoods, derived from different types of trees, are distinguished by their leaf structures and cellular compositions, each serving unique purposes in construction and manufacturing. Softwoods come from cone-bearing trees with needle-like leaves and are predominantly composed of longitudinal cells called tracheids and a smaller proportion of radial cells known as rays. Due to their cellular structure, softwoods are commonly used in construction for structural frames, sheathing,...
260
UV–Vis Spectrum
1.4K
When light passes through a substance, a portion of the light is absorbed while the remaining light is reflected or transmitted. If the molecule absorbs light between the wavelengths of 180–400 nm range, the UV spectrum is obtained, and if it absorbs light in the 400–780 nm wavelength range, the visible spectrum is obtained.
The UV–Vis spectrum of a molecule is the plot of its absorbance versus wavelength. The plot is drawn by taking molar...
The UV–Vis spectrum of a molecule is the plot of its absorbance versus wavelength. The plot is drawn by taking molar...
1.4K


