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调整铁的陶金属透性,以便在质子陶细胞中有效和持久的氧化和进化

Mingxuan Dai^1,2, Yongcheng Tong², Wentao He¹

¹Deep Space Exploration Laboratory, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.

ACS applied materials & interfaces

|June 16, 2025

概括

将氧化物 (GDC) 引入-硫酸 (Ni-BZCY) 陶中,显著提高了质子陶细胞的耐用性. GDC提高了陶金属的湿透性,提高了燃料应用的微结构稳定性和催化性能.

科学领域:

材料科学材料科学材料科学
电化学电化学电化学
催化剂是一种催化剂.

背景情况:

质子陶电池提供高效的电气燃料转换.
陶电极 (Ni-BZCY) 对反应具有很高的活性.
由于陶金属的湿透性差,性能降低阻碍了实际使用.

研究的目的:

为了提高对质子陶电池的Ni-BZCY陶的催化耐用性.
调查氧化物 (GDC) 在提高陶金属接口性能方面的作用.
了解增强微观结构稳定性和催化活性背后的机制.

主要方法:

将GDC纳入Ni-BZCY陶矩阵.
阶段场建模以评估微观结构稳定性.
密度函数理论 (DFT) 对界面相互作用的计算.
对称质子陶电池的制造和测试.

主要成果:

在热力学上,GDC的引入促进了Ni/BZCY的湿透性和微观结构的稳定性.
与Ni-BZCY相比,DFT计算显示了更强的Ni-GDC相互作用和更高的Ni湿度.
用GDC修改的电极在700°C时实现了7.37mL·min−1·cm−2的稳定H2流.
经证实稳定运行,电能消耗低 (0.90 kWh·Nm-3).

结论:

接口可湿性对于异质电催化剂的耐用性至关重要.
GDC 作为一个有效的固元件,增强 Ni-BZCY 陶的稳定性.
这种方法为设计用于能源应用的耐用催化剂提供了洞察力.

关键词:

尼克莱陶是一种陶.陶 - 金属的湿透性氧化和进化反应的反应.界面稳定性界面稳定性质子陶电池是一种质子陶电池.

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