考虑动力因子的静态滴水蒸发的严格模型
1Institute of the Earth Cryosphere, Tyumen Scientific Center, Siberian Branch of the Russian Academy of Sciences, P.O. Box 1230, 625000 Tyumen, Russia.
Physical review. E
|June 19, 2025
概括
一个新的模型准确地描述了液滴蒸发,考虑了扩散和动力学,没有接触角的纠正. 实验证实了它的精度,强调了在蒸发研究期间需要环境隔离的必要性.
科学领域:
- 热力学和质量转移
- 流体动力学 流体动力学
背景情况:
- 滴蒸发在各种科学和工业应用中至关重要.
- 现有的模型通常依赖于经验接触角度的校正,限制了它们的基本准确性.
研究的目的:
- 开发一种严格的分析模型,用于同热性静止液滴蒸发.
- 研究扩散和内在动力学对蒸发速率的影响.
- 在没有经验参数的情况下分析蒸发模式和模式.
主要方法:
- 基于扩散质量转移理论开发了一种新的分析模型.
- 将内在的蒸发动力学纳入模型.
- 分析了扩散动力,扩散和动力蒸发模式.
- 考虑恒定接触半径 (钉钉) 和恒定接触角度模式.
主要成果:
- 该模型准确地预测了无接触角度校正参数的静止滴蒸发.
- 确定了不同的蒸发模式:扩散动力,扩散和动力.
- 乙醇和水蒸发的实验数据验证了模型的预测.
- 证明了将实验装置与周围大气隔离的必要性.
结论:
- 提出的模型提供了一个更严格,更准确的关于状滴滴蒸发的描述.
- 环境隔离对于获得有关滴水蒸发动性的可靠实验数据至关重要.
相关概念视频
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
454
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
454
Phase Transitions: Vaporization and Condensation
18.8K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase...
18.8K
Theories of Dissolution: Diffusion Layer Model
960
Dissolution, the process by which drug particles dissolve in a solvent, is explained by the diffusion layer model, a theoretical framework that simulates the absorption of oral drugs and allows us to analyze experimental data.
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
960
Vapor Pressure of Fluid
1.5K
The vapor pressure of a fluid is a crucial concept in fluid mechanics, influencing phenomena such as boiling and cavitation. Vapor pressure refers to the pressure exerted by a vapor at a state of thermodynamic equilibrium with its corresponding liquid phase at a specific temperature. It represents the tendency of molecules to escape from the fluid surface into the vapor phase.
When a liquid is placed in a closed container with a small air space, and the space is evacuated, vapor molecules will...
When a liquid is placed in a closed container with a small air space, and the space is evacuated, vapor molecules will...
1.5K
Distillation: Vapor–Liquid Equilibria
3.0K
Distillation is a separation technique that takes advantage of the boiling point properties of disparate elements in a mixture. To perform distillation, we begin by heating a miscible mixture of two liquids with a significant difference in boiling points (at least 20°C). As the solution heats up and reaches the bubble point of the more volatile component, some molecules of the more volatile component transition into the gas phase and travel upward into the condenser, which is a glass tube...
3.0K
Kinetic Theory of an Ideal Gas
3.7K
A mole is defined as the amount of any substance that contains as many molecules as there are atoms in exactly 12 grams of carbon-12. An Italian scientist Amedeo Avogadro (1776–1856) formed the hypothesis that equal volumes of gas at equal pressure and temperature contain equal numbers of molecules, independent of the type of gas. Later, the hypothesis was developed to form the SI unit for measuring the amount of any substance.
The number of molecules in one mole is called...
The number of molecules in one mole is called...
3.7K


