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具有不同素终端组的非对称非烯受体,用于高效逆矿太阳能电池的有效被动化

Bingxue Pi¹, Yue Qiao¹, Ciyuan Huang¹

¹Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, MOE Key Laboratory of New Processing Technology for Non-ferrous Metals and Materials, School of Chemistry and Chemical Engineering, School of Resources, Environment and Materials, Nanning, 530004, China.

Small (Weinheim an der Bergstrasse, Germany)

|June 19, 2025

概括

不对称的有机分子有效地抑制矿太阳能电池 (PSC) 中的缺陷. SY1分子增强了缺陷被动化,导致在反向PSC中高功率转换效率 (PCE) 为25.63%.

科学领域:

材料科学材料科学材料科学
可再生能源可再生能源是可再生能源.
有机电子有机电子

背景情况:

矿太阳能电池 (PSC) 的接口问题阻碍了效率和稳定性.
有效的缺陷被动化对于提高PSC性能至关重要.
不对称的有机分子在PSC中缺陷被动化方面未得到充分研究.

研究的目的:

研究不对称的有机分子 (SY1,SY2) 和对称的分子 (Y6) 在反向PSC中作为被动剂的影响.
为了将分子结构与被动化效率和设备性能相关联.
优化矿层的性能,以提高太阳能电池的效率.

主要方法:

合成和引入非对称 (SY1,SY2) 和对称 (Y6) 有机分子.
矿薄膜的特性,包括分子方向和结晶的表征.
倒置PSC装置的制造和性能测试.

主要成果:

由于其不对称的结构和替代,SY1促进了面对面的方向,并促进了谷物边界被动化.
与SY2和Y6.6相比,SY1表现出较高的缺陷和粒度边界被动化.
基于SY1的设备实现了25.63%的功率转换效率 (PCE),超过了SY2 (24.12%) 和Y6 (24.70%) 的设备.

结论:

不对称的分子设计是开发PSC中有效的被动剂的有希望的策略.
分子结构显著影响矿膜质量和设备性能.
SY1代表了高效率倒置PSC的新和有效的被动器.

关键词:

迪普洛的时刻迪普洛的时刻分子晶体性分子晶体性矿太阳能电池是如何使用的剩余压力是一种残留压力.对称和不对称的对称性和不对称性.

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