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卢米桑托尼的化骨重组:选择的意外双重作用

Ferdinand Woge1, Muyuan Wang1, Brandon White2

  • 1Department of Chemistry, Johns Hopkins University, 3400 N. Charles St., Baltimore, Maryland 21218, United States.

The Journal of organic chemistry
|June 19, 2025
PubMed
概括

合成化学家们使用Selectfluor实现了一种新的化骨重组,使用Selectfluor. 机械研究揭示了一个令人惊的热两电子过程,产生独特的化乳衍生物.

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Bromination and chlorination of aromatic rings by electrophilic aromatic substitution reactions are easily achieved, but fluorination and iodination are difficult to achieve. Fluorine is so reactive that its reaction with benzene is difficult to control, resulting in poor yields of monofluoroaromatic products. To address this, Selectfluor reagent is used as a fluorine source in which a fluorine atom is bonded to a positively charged nitrogen.
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