超导性在转移稳定的K1+δMo6Se8:一个间隔的谢弗雷尔阶段
Yun-Qing Shi1,2, Xiao-Ping Ma1, Le-Wei Chen1,2
1Institute of Physics and Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100190, China.
研究人员合成了一种新的间隔的Chevrel相 (K1+δMo6Se8),在8.9K时表现出大量超导.这一发现扩大了高临界场超导体的范围,并提供了新的合成途径.
科学领域:
- 材料科学
- 凝聚物质物理学
- 固态化学
背景情况:
- 具有Mo6X8结构的Chevrel相 (CP) 在能源和超导应用中显示出希望.
- 合成新的 CP 衍生物是很困难的,因为电离体间隔破坏了晶格的稳定性,特别是在化物和化物中.
研究的目的:
- 合成一种新型的热力学转移稳定的雪佛兰相化合物,K1+δMo6Se8.
- 为了研究这种新材料的超导特性.
主要方法:
- 固态反应合成
- 用X射线结晶学进行结构测定.
- 电阻,磁化和特异性热量测量用于表征.
主要成果:
- 成功合成K1+δMo6Se8 (δ ≈ 0.37) 具有三临床结构 (空间组P1̅).
- 在8.9K的临界温度 (Tc) 中观察散装超导.
- 估计的上临界场为26.4 T,超过了保利磁性极限,表明多间隙超导.
结论:
- K1+δMo6Se8扩大了高临界场超导雪佛兰相的家族.
- 低温固态反应为合成新型CP材料提供了可行的途径.
更多相关视频
04:51Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
Published on: July 8, 2021
06:53Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
相关概念视频
Types Of Superconductors
Superconductor
Phase Transitions: Sublimation and Deposition
Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Ferromagnetism
Phase Transitions: Melting and Freezing
