固化方法对微观结构,机械性能和重金属固定在非化MSWIFA型轻质聚合物的固化方法的影响
Ximeng Wu1, Haifeng Wang2, Weichao Guo1
1State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, Hebei, China; Hebei Province Engineering Research Center for Harmless Synergistic Treatment and Recycling of Municipal Solid Waste, Yanshan University, Qinhuangdao, 066004, Hebei, China.
Environmental research
|June 22, 2025
概括
从城市固体废物焚烧飞灰 (MSWIFA) 和碳化物渣制成环保的非烧结轻质聚合物. 最佳的蒸汽固化条件产生了符合中国标准的聚合物,表现出良好的机械性能和重金属固定性.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 城市发展 城市发展
背景情况:
- 固体废物回收对于环境友好的城市发展至关重要,因为经济快速增长和城市化.
- 了解固化环境对重金属固定和MSWIFA冷结合聚合物的机械性能的影响至关重要.
- 目前对MSWIFA和碳化物渣的非烧结聚合物和碳化物渣的现有研究需要进一步研究固化效应.
研究的目的:
- 使用城市固体废物焚烧飞灰 (MSWIFA) 和碳化物渣来生产环保的非烧结轻质聚合物.
- 研究固化温度和溶液对这些聚合物的性能,反应产品和重金属浸的影响.
- 优化固化条件,以达到所需的机械强度和环境性能.
主要方法:
- 使用的城市固体废物焚烧飞灰 (MSWIFA) 和碳化物渣用于聚合物生产.
- 调查了各种固化温度和溶液,包括蒸汽固化和碳化渣超.
- 采用了先进的特征技术,如X射线衍射 (XRD),里埃变换红外光谱 (FTIR),扫描电子显微镜 (SEM) 和X射线光电子光谱 (XPS).
主要成果:
- 聚合物在60°C的蒸汽固化下使用碳化渣渣超水剂12小时达到超过7.02MPa的机械强度,符合中国轻质聚合物标准.
- 蒸汽固化促进了矿石矿物质的形成,在60°C时得到最佳结果,而更高的温度 (75°C) 削弱了这种效应.
- 微结构分析显示,高温激活了渣渣的反应性,加速了C-S-H凝和化酸生成,增强了聚合物的性能.
结论:
- 由MSWIFA和碳化物渣生产的非化轻质聚合物具有出色的机械性能和环境适应性.
- 优化的蒸汽固化条件对于最大限度地提高聚合物的强度和最大限度地减少重金属漏至关重要.
- 这些聚合物为天然聚合物提供了可持续的替代品,有助于环保建筑材料和废物利用.
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