延迟膨胀聚合物微球用于CO2道控制在高温和高度环境下
Tianqi Liu1, Yan Zhang1, Yujun Feng1
1Polymer Research Institute, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, People's Republic of China.
ACS omega
|June 23, 2025
概括
新的延迟膨胀聚合物微球 (DVP) 控制二氧化碳气体通道. 这些微球通过在恶劣条件下有效地堵塞多孔介质来改善石油回收和二氧化碳储存.
科学领域:
- 石油工程是石油工程中的一个.
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 在二氧化碳泛滥期间的气体通道减少了石油回收和二氧化碳储存效率.
- 现有的聚合物微球迅速和不受控制地膨胀,阻碍了深层运输,并在高温,高盐度环境中插入.
- 需要先进的材料来管理在具有挑战性的地下条件下的气体通道.
研究的目的:
- 开发二氧化碳触发和延迟膨胀聚合物微球 (DVP) 以有效控制气体通道.
- 调查单体组成和交叉链接剂含量对DVP属性的影响.
- 评估DPV在提高石油回收和二氧化碳储存方面的表现.
主要方法:
- 通过使用DMAPMAm,NVP和MBA的逆微乳液聚合合成DPP.
- 在不同条件下的水溶液中研究了DVP形态和胀行为.
- 在模拟储条件下的人工核心中评估气体通道控制能力.
主要成果:
- 随着DMAPMAm和交叉链接器的含量,DVP膨胀率增加,高达0.5%的MBA.
- 陈旧的DVP (8天,140°C,15,000毫克/升盐水) 的膨胀比为2.50 (280至701 nm).
- 在现场老化后,DVP在破裂的核心 (10mD透率) 中实现了99%的插塞效率.
结论:
- 开发的CO2触发,延迟膨胀的聚合物微球在恶劣环境中表现出色.
- DVP有效地控制了天然气输送,为增强石油回收和二氧化碳储存提供了有前途的解决方案.
- 这项研究为设计用于地下应用的先进材料提供了一种新的方法.
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