在可变形材料中发现隐藏的顺序:的案例
Zeyu Qiao1, Kun Lin1, Sergii Khmelevskyi2
1Institute of Solid State Chemistry, Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, China.
研究人员使用零重力合成方法在dysprosium金属中发现了一个隐藏的低对称的正方形相. 这一发现挑战了公认的结构,并揭示了稀土材料特性.
科学领域:
- 材料科学
- 凝聚物质物理学
- 晶体学
背景情况:
- 可变形材料的内在秩序往往被格子缺陷所掩盖.
- 了解这些隐藏的顺序对于推进物质性质至关重要.
- 金属是具有潜在功能应用的关键稀土元素.
研究的目的:
- 开发一种合成高晶度,无应力可变形材料的方法.
- 为了确定金属的内在原子和轨道顺序.
- 阐明稀土材料中磁弹性扭曲的潜在机制.
主要方法:
- 从可变形材料中合成微球的零重力.
- 高分辨率的晶体分析.
- 第一个原则是结晶场理论的计算.
主要成果:
- 制造高度结晶的,几乎没有压力的微球.
- 在dysprosium中识别出与公认的六角结构 (P63/mmc) 不同的内在低对称的正交相 (Cmcm).
- 在Dy的4f电子外中确定非零四极运算子,解释Cmcm阶段并与terbium的行为对比.
结论:
- 的内在结构是一个由轨道顺序驱动的正方形Cmcm相.
- 这些发现为稀土材料的磁弹性效应提供了新的理解,这与巨型磁阻相关.
- 在其他可变形材料中发现隐藏的秩序.
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