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Updated: Sep 18, 2025

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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下一代金属有机框架研究的人工智能范式

Aydin Ozcan1,2, François-Xavier Coudert3, Sven M J Rogge4

  • 1TUBİTAK Marmara Research Center, Materials Technologies, Gebze, Kocaeli 41470, Türkiye.

Journal of the American Chemical Society
|June 24, 2025
PubMed
概括

大型语言模型 (LLM) 通过自动化文献审查和数据提取来改变金属有机框架 (MOF) 研究. 这项技术加速了材料的发现,并承诺在自动化材料开发方面取得进一步的进步.

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Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
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