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在高盐废水中通过表面复合物介导的电子转移在Ce-doped CuO上对醇的选择性聚合

Wenjing Xie¹, Zhenxin Wang¹, Yifan Yin¹

¹Shaanxi Key Laboratory of Environmental Engineering, School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an, Shaanxi, 710055, China.

|June 24, 2025

概括

一种新的非激进电子转移策略使用基化CuO和过氧化硫酸盐将醇聚合成固体,有效地将其从高盐废水中去除,没有有毒的副产品.

科学领域:

环境化学环境化学
材料科学材料科学材料科学
催化剂是一种催化剂.

背景情况:

传统的基于激素的先进氧化过程,由于氧化剂需求和激素火,在高盐废水中与醇去除作斗争.
挑战包括副产品的形成和高盐度工业废水的低效率.

研究的目的:

开发一种非根性电子转移聚合策略,以高效地去除二.
为了研究用配合的中性CuO (Ce-CuO) 与过氧化硫酸盐 (PDS) 处理高盐废水的使用.

主要方法:

使用表面激活的Ce-CuO@PDS复合物选择性氧化4-二 (4-CP) 成为基.
研究了电子转移过程,专注于界面氧气空缺及其在增强电子转移中的作用.
评估了在高盐度条件下和在造纸厂废水中战略的表现.

主要成果:

通过使用低PDS剂量,实现100%的4-CP去除与86.4%的总有机碳转化为聚合物.
证实了电子转移过程对基因通路的优势,归因于Ce-CuO中的氧空缺.
在高度条件下 (3000-10,000毫克L-1Cl-) 和在工业废水中进行选择性清除中表现出强大的性能.

结论:

电子转移聚合策略提供了一种可持续的方法来处理高盐度废水中的耐火有机物.
Ce-CuO催化剂提高了电子转移效率,导致有效的二醇消除和聚合物形成.
与基于矿化方法相比,这种方法显著降低了氧化剂的消耗.

关键词:

有添加的CuO与相合.基醇的聚合聚合.电子转移路径的电子转移路径过盐废水处理的超盐废水处理方法非基的氧化非基的氧化

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