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用于矿太阳能电池的化和无剂孔运输材料

Wei Yu^1,2, Xiafei Cheng³, Qiaoyun Chen¹

¹College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China.

ACS applied materials & interfaces

|June 24, 2025

概括

用替代的孔输送材料 (HTM) 显著提高矿太阳能电池 (PSC) 的性能和稳定性. 基于的HTMPM-2F实现了24.27%的效率,并在3500小时后保持了85%,超过了基于的替代品.

科学领域:

材料科学材料科学材料科学
有机电子有机电子
太阳能光伏发电是如何实现的

背景情况:

孔运输材料 (HTM) 对于高效的矿太阳能电池 (PSC) 性能至关重要.
将素纳入基于聚合物的HTM可以提高充电传输和设备效率.
开发稳定和高性能的HTM是推进PSC技术的关键.

研究的目的:

合成和研究三种基于聚合物的HTM,具有不同的素替代物 (和).
系统地评估素数量和类型对HTM特性和PSC性能的影响.
评估使用这些新型HTM的PSC的长期稳定性.

主要方法:

三种化聚合物HTM的合成:PM-2F,PM-4F (替代) 和PM-4Cl (替代).
描述HTM属性,包括能量水平,孔移动性和电导率.
使用合成HTMs的PSC设备的制造和测试.
在气氛下测试PSC装置的长期稳定性.

主要成果:

与PM-4Cl.相比,用替代的HTM (PM-2F,PM-4F) 显示出较低的HOMO能量水平,增强的孔移动性和优越的导电性.
PM-2F的功率转换效率达到24.27%,PM-4F的功率转换效率达到21.08%,明显高于基对应物.
用替代的设备在3500小时后保留了85%的初始效率,而用替代的设备在700小时后降解到30%左右.

结论:

聚合物HTM中的替代在提高矿太阳能电池的效率和长期稳定性方面非常有效.
由于优化了能量对齐和降低了硬体障碍,PM-2F表现出卓越的性能,使其成为高性能PSC的有希望的候选人.
该研究强调了素工程在HTMs中对于稳定和高效的有机太阳能电池技术的发展的关键作用.

关键词:

D-A结合聚合物的聚合物.替代的替代方法穿孔运输材料的运输材料有机材料有机材料有机材料矿太阳能电池是如何使用的

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