使用过的石墨阳极通过缩的硫酸进行可持续的回收利用
Shiwen Gong1, Qiming Zhao1, Yuxin Fan1
1Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China.
Small (Weinheim an der Bergstrasse, Germany)
|June 25, 2025
概括
回收使用的离子电池 (LIB) 石墨阳极至关重要. 使用缩硫酸的新方法有效地恢复石墨,提高其性能并使其能够重复使用,提供经济和环境效益.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 环境科学 环境科学
背景情况:
- 离子电池 (LIB) 越来越普遍,导致使用过的电池数量增加.
- 回收LIBs对于环境保护,安全和资源可持续性至关重要.
- 与阴极材料相比,石墨阳极回收往往被忽视,因为其经济价值较低.
研究的目的:
- 开发一种简单,环保,低成本的废旧石墨阳极的再循环利用策略.
- 恢复和修改石墨阳极,提高它们的电化学性能.
- 为了证明使用缩硫酸用于石墨阳极再生的技术和经济可行性.
主要方法:
- 使用过的石墨阳极用缩的硫酸处理.
- 该过程消除了杂质,并引入了含氧的功能组.
- 剩余的有机成分被碳化,形成无形碳涂层.
主要成果:
- 上循环的石墨具有高的特异容量 (391 mAh g-1),超过原始石墨的理论容量 (372 mAh g-1).
- 观察到出色的速率能力和稳定的循环能力,在0.2°C的100个循环后,约100%的容量保留.
- 缩的硫酸至少在5个循环中被成功重复使用,证实了其在再生过程中的可行性.
结论:
- 展示了一种可持续的综合方法,用于再生和再循环使用过的石墨阳极.
- 该方法提供了显著的经济,战略和生态优势.
- 这种上循环策略提高了石墨阳极性能,并促进了资源的可持续性.
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