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在雄性大鼠中,tributyltin改变了血清胆汁酸池的组成

Wenhuan Yao1,2, Jinjiao Luan1, Hui Li1,2

  • 1Institute of Preventive Medicine, School of Public Health, Cheeloo College of Medicine, Shandong University, Jinan 250012, China.

Toxics
|June 25, 2025
PubMed
概括

作为一种内分泌干扰剂的三乙烯 (TBT) 改变了大鼠的胆汁酸 (BA) 循环,特别是减少了 taurine 结合的 BA. 这项研究突出了TBT的重点.

关键词:
在UHPLC-MS/MS中使用.胆汁酸 胆汁酸 胆汁酸肝脏 肝脏 肝脏 肝脏 肝脏 肝脏致敬林林的人民

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride01:26

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
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