静电自组装碳黑相变微囊用于建筑光热转换和热能储存
XiaoFeng Wu1,2, YaZhou Zhang1, Ting-Ting Li1,2
1School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.
Langmuir : the ACS journal of surfaces and colloids
|June 25, 2025
概括
研究人员开发了碳黑相变微囊 (CB-MPCMs),用于增强光热能储存. 这些微体表现出稳定的性能和在建筑热管理系统中改进的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 储能 储能 储能 储能 储能 储能
背景情况:
- 变相材料 (PCM) 对于热能存储至关重要,但在实际应用中经常面临挑战.
- 提高PCM的光热反应和稳定性对于高效的太阳能利用至关重要.
- 开发强大的微封装技术是防止泄漏和随着时间的推移保持性能的关键.
研究的目的:
- 开发新的碳黑相变微囊 (CB-MPCMs),具有改进的光热转换和储热能力.
- 通过将CB-MPCMs固定在灵活的基板上来创建稳定的复合材料,用于建筑热管理.
- 评估在循环照射下制造的CB-MPCM复合板的性能和耐用性.
主要方法:
- 静电自组合聚合被用来合成石 (PW) 核心和/碳黑 (CB) 微囊.
- CB-MPCM的特点是其热储性能,封装效率和高达80.0°C的热稳定性.
- 使用环氧树脂 (ER) 和固化剂 (CA) 将CB-MPCM集成到无布基板上,形成带有聚碳酸 (PC) 外层的复合板.
主要成果:
- 合成的CB-MPCM表现出大约130.0Jg-1的高相变和超过60%的封装效率.
- 微囊表现出极好的热稳定性,在高温下保持无泄漏性,并在多个循环后保持稳定的相变度.
- 由此产生的CB-MPCM复合板在循环照射下显示出显著的能量储存和释放特征 (1kW m-2),表明性能稳定.
结论:
- 静电自组装方法为生产高性能CB-MPCM提供了一个简单而有效的途径.
- 开发的CB-MPCM复合板为建筑热管理提供了一个有前途的解决方案,增强节能和太阳能收集.
- 这些微封装的相变材料在可持续能源技术中具有广泛的应用前景.
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