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伊利西蒙尼A的总合成

Liangchao Zhu1, Jinrui Li1, Zhaohong Lu1

  • 1Key Laboratory of Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

Journal of the American Chemical Society
|June 26, 2025
PubMed
概括

研究人员实现了Illisimonin A的总合成,这是一个复杂的类. 这种14个步骤的合成利用了新的循环添加和化策略来构建其复杂的五环结构.

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Basicity of Heterocyclic Aromatic Amines

Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).
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