选择最优的计算方法和化学试剂在青材料的表面能量测试
Longchang Niu1,2, Chongzhi Tu1, Gongying Ding1
1School of Civil Engineering and Architecture, Wuyi University, Jiangmen 529020, China.
Materials (Basel, Switzerland)
|June 27, 2025
概括
本研究介绍了青表面能量计算的总最小平方法,提高了精度. 它还确定WFSD是最佳的试剂组合,大大减少了评估青聚合物粘附耐久性的错误.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 土木工程 土木工程是指土木工程.
背景情况:
- 在青材料中,不准确的表面能量计算威胁到对青聚合物的粘附耐久性的评估.
- 经典最小平方 (LS) 方法和随意的试剂选择导致结果不稳定.
研究的目的:
- 为了解决青表面能量计算方法中的不准确性.
- 建立一个合理的基础来选择化学试剂组合,以提高准确性.
主要方法:
- 用同步方程来计算青表面能量参数.
- 使用总最小平方 (TLS) 方法,将其与经典最小平方 (LS) 方法进行比较.
- 根据物理特征,跳跃度和异常值评估试剂组合.
主要成果:
- 与经典最小方程 (LS) 相比,总最小方程 (TLS) 方法显著减少了安装错误.
- 试剂组合WFSD (蒸水+形式胺+二甲基硫氧化物+二甲基甲) 证明是最佳的,产生准确的结果,没有异常值.
- 与WFEG计划相比,WFSD计划在两个青类型中减少了总表面能量的计算错误率17.71%和64.80%.
结论:
- 总最小平方 (TLS) 方法提高了青表面能量计算的准确性和稳定性.
- WFSD试剂组合为量化青表面能量提供了一种可靠和准确的方法.
- 这项研究建立了一个强大的框架来评估青聚合物的粘附耐用性,减轻试剂依赖的变化.
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