用于热固化木材粘合剂的调聚醇:"A1"类非异酸聚氨来自凝结宁的聚氨
Gopakumar Sivasankarapillai1,2, Arsène Bikoro Bi Athomo1,2, Detlef Schmiedl3
1Freiburg Materials Research Centre, University of Freiburg, Stefan-Meier-Strasse 21, D-79104 Freiburg i. Br., Germany.
Journal of agricultural and food chemistry
|June 27, 2025
概括
研究人员从Quebracho凝结素 (CT) 开发出环保的木材粘合剂. 这些非异酸聚氨 (NIPU) 符合欧洲标准的干粘强度,为传统粘合剂提供可持续的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续化学 可持续化学
背景情况:
- 传统的木材粘合剂通常含有甲或异酸盐,造成环境和健康问题.
- 来自Quebracho的冷凝素为开发生物基聚合物提供了一种可再生资源.
- 非异酸聚氨 (NIPU) 是比传统聚氨更安全的替代品.
研究的目的:
- 开发新的非异酸聚氨 (NIPU) 木材粘合剂,使用奎布拉科凝结素 (CT).
- 综合和描述两个不同的NIPU配方:TANIPU-DA和TANIPU-DA-TD.
- 根据欧洲标准,评估这些以素为基础的NIPU作为木材粘合剂的性能.
主要方法:
- 用二甲基碳酸盐碳化CT,然后用多功能氨基 (六甲基二胺和六甲基氨酸) 凝结.
- 使用富里埃变换红外光谱 (FTIR) 测量,粘度测量和尺寸排除色谱 (SEC) 确认尿的形成.
- 使用动态机械分析 (DMA) 分析凝和玻璃化温度.
- 评估木质结合组件的膝盖剪切强度和湿强度.
主要成果:
- 两种NIPU配方TANIPU-DA和TANIPU-DA-TD已经成功合成.
- 确认了尿的形成,并描述了热过渡 (凝和玻璃化).
- 塔尼普-DA-TD实现了超过10N/mm2的腰剪强度,符合"A1"类木材粘合剂的欧洲标准.
- 这两种配方均表现出显著的湿强度 (TANIPU-DA 的2.5 ± 1.3 N/mm2,TANIPU-DA-TD 的3.8 ± 1.2 N/mm2).
结论:
- 基于坦宁的NIPU可以满足木材粘合剂严格的干粘合强度要求.
- 这些NIPU代表了传统的甲和异酸盐木材粘合剂的有希望的,环保的替代品.
- 这项研究强调了利用天然色素在开发高性能,可持续的粘合材料方面的潜力.
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