溶剂组成对一维 (NH4) 2V10O25·8H2O电活性材料对电化学储存应用的溶剂组成的影响
Poria Gomrokchi1, Maryam Ghiyasiyan-Arani1, Elmuez A Dawi2
1Institute of Nano Science and Nano Technology, University of Kashan Kashan 87317-51167 Islamic Republic of Iran m.ghiyasiyan@kashanu.ac.ir salavati@Kashanu.ac.ir +98 31 55913201 +98 31 55912383.
为了增强存储,合成了一维的纳米电极材料. 甲酸水合物阶段表现出卓越的性能,达到5268mAhg-1的最大容量.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 基于的材料对储存有希望,但电导性差.
- 定制电极材料形态,特别是在一维 (1D) 的纳米结构,可以提高电化学性能.
- 溶热法为合成多种氧化物纳米结构提供了一种多功能途径.
研究的目的:
- 为了合成和表征1D纳米电极材料用于储存.
- 研究不同合成条件对材料形态和相纯度的影响.
- 评估各种基于的纳米结构的储能.
主要方法:
- 溶热合成产生1D纳米棒.
- 使用XRD,FT-IR,EDX,FE-SEM,TEM和BET分析进行结构和形态表征.
- 电化学电荷-放电测试以评估储能容量.
主要成果:
- 合成产生的六甲酸盐 ((NH4) 2V6O16) 和甲酸盐水合物 ((NH4) 2V10O25·8H2O) 结构具有不同的形态.
- (NH4) 2V10O25·8H2O纳米物质在第7个周期表现出高容量5268mA h g-1和956mA h g-1在15个周期后.
- (NH4) 2V6O16显示了一个较低的容量324mAhg-1 .
- (NH4) 2V10O25·8H2O的优化纳米基结构的表面积为23.571m2g-1.
结论:
- 设计1D纳米结构显著提高了基电极的储能效率.
- 甲酸水合物 ((NH4) 2V10O25·8H2O) 在一个纳米基质的形态是一个非常有效的材料储存.
- 阶段纯度和形态是影响这些电极材料电化学性能的关键因素.
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