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Updated: Sep 17, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
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Published on: October 5, 2019

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用改性金属有机框架合成过氧化

Boya Tang1, David Brooks1, Meng He1

  • 1Department of Chemistry, University of Manchester, Manchester M13 9PL, U.K.

Journal of the American Chemical Society
|July 1, 2025
PubMed
概括

这项研究引入了由改性金属有机框架 (MOF),用于从氧气中有效的光催化过氧化 (H2O2) 合成. 新的Re10-MFM-67材料在可见光下显示出高的生产率和周转频率.

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
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