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相关概念视频

Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Valence Bond Theory02:42

Valence Bond Theory

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Ions as Acids and Bases02:54

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Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
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Ionic Compounds: Formulas and Nomenclature03:34

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An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
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In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
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Updated: Sep 17, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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一个质子或氧化物离子导体?

Sara Adeeba Ismail1, Kazuaki Toyoura2, Lulu Jiang1

  • 1College of Energy, Soochow University, No 1 Shizi Street, Gusu District, Suzhou 215006, China.

Journal of the American Chemical Society
|July 1, 2025
PubMed
概括

Ba7Nb4MoO20是一种纯氧化离子导体,而不是质子导体. 通过释放离子,水化可以在更高的温度下增强氧化离子导电性.

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科学领域:

  • 固态化学
  • 材料科学
  • 离子导电

背景情况:

  • Ba7Nb4MoO20是一个有前途的快速氧化离子导体.
  • 之前的研究表明在潮湿的气氛中进行质子导电,

研究的目的:

  • 在不同湿度下澄清Ba7Nb4MoO20的导电机制.
  • 研究水分对离子导电性的作用.

主要方法:

  • 理论计算以评估质子的移动性
  • 在高达800°C的电动力 (EMF) 测量.
  • 分析H2O/D2O同位素的影响.

主要成果:

  • 理论和实验证据显示质子的移动性很小.
  • Ba7Nb4MoO20主要表现出氧化离子导电.
  • 化稳定了间位氧化物离子,最初降低了导电性 (<400°C).
  • 在400°C以上,通过促进质子注入和释放氧化离子来增强氧化离子导电性.

结论:

  • 证实Ba7Nb4MoO20是一种近纯氧化离子导体.
  • 水起着复杂的作用,可能会在高温下增强氧化离子导电.