在隔离和住宅站中增加了PFAS前体
Michael Penrose1, Jacob Deighton2, Susan T Glassmeyer3
1ORISE Participant at Center for Environmental Solutions & Emergency Response, U.S. Environmental Protection Agency, Cincinnati, Ohio 45220, United States.
概括
住宅废水是多和多基基物质 (PFAS) 的重要来源. 污水管道系统充当PFAS水库,构成地下水污染风险,而站会导致偶尔的尖峰,影响处理.
科学领域:
- 环境化学环境化学
- 环境科学 环境科学
- 废水工程 废水工程
背景情况:
- 住宅废水是未被认可的和多基基物质 (PFAS) 的来源.
- 像污水池和站这样的分散系统是PFAS管理的关键点.
- 了解这些系统中的PFAS行为对于环境保护至关重要.
研究的目的:
- 为了比较分离与站废水中的per-和多醇基物质 (PFAS) 度和前体.
- 评估总可氧化前体 (TOP) 测定在评估住宅废水中PFAS污染物的有效性.
- 确定污水系统和站在PFAS运输和潜在地下水污染中的作用.
主要方法:
- 分析了70个per-和多基基物质 (PFAS) 及其前体.
- 应用总可氧化前体 (TOP) 试验来评估可氧化PFAS.
- 直接比较PFAS含量从污泥系统和站废水中排泄的污水.
主要成果:
- 与站 (84.2 ng/L) 相比,Septage在TOP后的PFAS中位数度 (687.5 ng/L) 显著更高.
- 观察到FTCA的完全氧化和二PAP的不完全氧化,受有机负荷的影响.
- 污水管道系统充当PFAS水库,增加地下水污染风险,而站则会导致PFAS偶尔出现峰值.
结论:
- 井系统和站在住宅废水中的PFAS的命运和运输中发挥着独特的作用.
- 前体分析对于准确的风险评估至关重要,因为它仅通过针对性的PFAS测量就揭示了严重的低估.
- 需要量身定制的分析方法和预处理技术来管理分散和集中废水系统中的PFAS风险.
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