通过在现场构建机械异质性来解决聚合物网络中的超弹性-粘合性冲突
Ping Zhang1, Haowei Ruan1, Qingxian Li1
1Shenzhen Key Laboratory of Soft Mechanics & Smart Manufacturing, Department of Mechanics and Aerospace Engineering, Southern University of Science and Technology, Shenzhen, China.
Nature communications
|July 2, 2025
概括
研究人员通过创建异质聚合物网络,开发出具有低歇斯底里和强粘合力的可拉伸材料. 这些材料结合了柔软的粘合表面和硬的,不粘合的散体,用于先进的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 机械工程 机械工程
背景情况:
- 可拉伸材料需要低歇斯底里和强粘合,这两者很难同时实现.
- 现有的材料往往会对另一种材料的特性产生影响,从而限制了它们的应用范围.
研究的目的:
- 为高超弹性和粘合性聚合物网络提出设计原则.
- 克服了在可拉伸材料中统一矛盾的机械性质的挑战.
主要方法:
- 设计具有粘性弹性粘接表面和超弹性非粘接散体的异质聚合物网络.
- 利用氧气抑制机制进行网络合成.
- 构建聚合相图并建立功率定律标准.
主要成果:
- 在聚乙烯-烯酸-联合烯酸) 网络中,达到的歇斯底里 <5% 和粘附能量 >300 J/m2.
- 证明了在过渡厚度以下的非线性粘附能量厚度关系.
- 验证了创建超弹性但粘合性材料的设计原则.
结论:
- 异质聚合物网络提供了一个可行的策略,用于创建具有低hysteresis和强粘合的材料.
- 这些新型材料在高循环,耐疲劳的软人机接口中具有潜在的应用.
- 该研究为设计具有量身定制的机械性能的先进伸缩材料提供了一个框架.
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