基于纸张的烯酸树脂层层的固化反应动力学 - - 从实验室测量到线内质量控制
Robert Zimmerleiter1, Jovana Kovacevic2, Gerhard Leitner3
1Research Center for Non-Destructive Testing GmbH, Altenberger Straße 69, 4040, Linz, Austria. robert.zimmerleiter@recendt.at.
Analytical and bioanalytical chemistry
|July 2, 2025
概括
近红外 (NIR) 光谱学有效监测了甲 (PF) 树脂固化. 这种技术可以实时在线质量控制大规模的基于纸张的PF层生产.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 溶解甲 (PF) 树脂对于生产基于纸张的层状材料至关重要.
- 了解干燥和固化动力学对于优化大规模生产至关重要.
- 现有的方法可能无法提供实时,内联监控功能.
研究的目的:
- 综合分析PF树脂的干燥和固化动力学.
- 评估各种热物理和光学技术对过程监控的适用性.
- 评估实施近红外 (NIR) 光谱技术实时质量控制的可行性.
主要方法:
- 热重力测量分析 (TGA)
- 不同扫描热量计 (DSC)
- 里叶变换的红外发达气体分析 (FTIR-EGA)
- 在反射几何学中近红外 (NIR) 光谱学.
- 整合TGA与同时进行NIR光谱的整合.
- 部分最小平方 (PLS) 回归建模的回归建模.
主要成果:
- 同时进行的TGA-NIR分析证明了NIR在过程监控方面的潜力.
- 一个基于NIR的工业实时测量设置成功实施.
- 与PLS回归相结合的NIR光谱学产生了非常有前途的结果.
- 尼尔射线光谱对于实时线内质量控制具有优势.
结论:
- 尼尔射线光谱是监测PF树脂固化的合适工具.
- 实时线上质量控制是可以实现的大规模PF层生产使用NIR.
- 这种方法为工业制造工艺提供了显著的优势.
关键词:
不同扫描热量计 (DSC)里叶变换的红外发达气体分析 (FTIR-EGA)在NIR光谱学中使用NIR光谱.过程分析技术 (PAT) 是一种分析技术.树脂固化 树脂固化热重力测量分析 (TGA)更多相关视频
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