具有高β相含量的BaTiO3/PVDF-TrFE复合材料的压电和介电反应
Andrea Otero1, María Jesús Sayagués2, Francisco Javier Romero1
1Departamento de Física de la Materia Condensada, Facultad de Física, Universidad de Sevilla-ICMS, Avda. Reina Mercedes, s/n, Sevilla 41012, Spain.
概括
在PVDF-TrFE聚合物中使用酸 (BaTiO3) 填充剂开发了柔性压电复合材料. 这些材料具有增强的压电特性,对于可适应的传感器和纳米发电机至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 灵活的压电材料对于先进的传感器,电子产品和纳米发电机至关重要.
- 提高像PVDF-TrFE这样的聚合物的压电反应是一个关键的研究领域.
- 纳入陶颗粒是改善聚合物压电性的有希望的策略.
研究的目的:
- 研究酸铁 (BaTiO3) 含量对PVDF-TrFE复合物特性的影响.
- 评估β相形成,结晶和压电/介电特性.
- 探索更绿色的合成方法,以改善材料分散.
主要方法:
- 在PVDF-TrFE中进行高能球磨,使BaTiO3在PVDF-TrFE中更绿色地分散.
- 压缩成型和后加工以形成复合材料.
- 阶段,晶度和压电系数的表征 (d33).
主要成果:
- 高能球磨加工产生了分散良好的复合材料,初始无形化.
- 在加工后恢复的结晶性,取决于BaTiO3填充剂含量.
- 观察到降低的抛光电压和增强的压电响应 (d33),特别是在40vol%BaTiO3.3的两步抛光方法下.
结论:
- BaTiO3-PVDF-TrFE复合材料为灵活的电子产品提供了增强的压电性能.
- 高能球磨是一种有效和环保的分散技术.
- 协同效应和优化抛光策略可以显著提高压电性能.
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