强烈磨砂石灰岩和石头石的颗粒大小分布和热分解与微观结构和结构变化相关联
Filipe B Marinho DE Barros1,2, Ulysses P DE Holanda Pereira1,3, Maria Júlia S Luis1
1Universidade Federal de Pernambuco, Departamento de Engenharia de Minas, Avenida da Arquitetura, s/n, Cidade Universitária, 50740-550 Recife, PE, Brazil.
Anais da Academia Brasileira de Ciencias
|July 3, 2025
概括
将石灰岩和石灰岩研磨成超细尺寸,揭示了不同的机制. 较细粒度的多洛石磨砂速度较慢,但经历了显著的结构变化,与石灰岩不同.
科学领域:
- 地质地质地质地质地质地
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 石灰石和石头石越来越多地用于超细尺寸的环保应用.
- 了解颗粒大小减小和聚合对于优化它们的使用至关重要.
研究的目的:
- 为了研究石灰岩和石灰岩的磨削行为和超细尺寸缩小.
- 为了比较磨砂极限,能量消耗和两种岩石类型的结构变化.
主要方法:
- 星球球磨 (干磨) 时间长达32小时.
- 使用激光散射,物理吸收,电子显微镜,X射线衍射,红外光谱和热分析进行分析.
- 测量静态硬度和晶体颗粒大小.
主要成果:
- 石灰岩在1小时内达到其研磨极限 (12微米),没有显著的结构变化.
- 多洛石在8小时内达到其研磨极限 (6微米),显示了晶格应变,晶体体大小和CO32-振动模式的显著变化.
- 石-阿拉戈尼特转化发生在强烈磨砂的多洛石中;其较低的磨砂速度归因于精炼的粒度.
结论:
- 在每个岩石类型的研磨极限之外,存在着不同的能量消散机制.
- 石灰岩表现出聚合/脱聚周期,而石灰岩表现出塑性变形和强烈的聚合生长.
- 磨砂行为受初始粒度和矿物学的影响,影响适用于超细应用的适用性.
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