Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

28.0K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
28.0K
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

44.8K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
44.8K
X-ray Crystallography02:18

X-ray Crystallography

24.2K
The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
24.2K
X-ray Diffraction of Biological Samples01:10

X-ray Diffraction of Biological Samples

4.1K
X-ray diffraction or XRD is an analytical tool that utilizes X-rays to study ordered structures such as crystalline organic and inorganic samples, polycrystalline materials, proteins, carbohydrates, and drugs.
According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are  scattered by the electron clouds around the sample atoms. The  X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal...
4.1K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Decreased Thigh Muscle Cross-Sectional Area Following Anterior Cruciate Ligament Injury Depends on Concomitant Meniscal Injury and Subject Sex.

Journal of orthopaedic research : official publication of the Orthopaedic Research Society·2026
Same author

Singlet fission mediates carotenoid-to-bacteriochlorophyll energy transfer in purple photosynthetic bacteria.

Nature chemistry·2026
Same author

Improved Stability and Brightness Following Iterative Redesign of a De Novo Biliprotein.

Biochemistry·2026
Same author

Second-Harmonic Hyper-Mie Optical Activity Enables Closed-Loop Chiral Photochemistry.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

Rational design of pigment-polymer antenna complexes.

Chemical science·2026
Same author

Second-harmonic chiroptical scattering spectroscopy from plasmonic nanohelices.

Optics express·2026

相关实验视频

Updated: Sep 17, 2025

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
07:24

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis

Published on: May 10, 2021

6.4K

在diF-TES-ADT中,微结构决定了晶度驱动的单片裂变效率.

Hoyeon Choi1,2, Stefan Skalsky1, David G Bossanyi3

  • 1Department of Physics and Astronomy and the Photon Science Institute, University of Manchester, Oxford Road, M13 9PL, Manchester, UK.

Scientific reports
|July 3, 2025
PubMed
概括

在基膜中单片裂变 (SF) 的效率取决于微观结构. 由于有利的电荷转移状态,高度结晶的区域显示了增强的SF,影响了整体太阳能性能.

更多相关视频

Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films
08:49

Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films

Published on: December 4, 2014

14.4K
Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
08:44

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene

Published on: August 22, 2017

7.8K

相关实验视频

Last Updated: Sep 17, 2025

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
07:24

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis

Published on: May 10, 2021

6.4K
Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films
08:49

Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films

Published on: December 4, 2014

14.4K
Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
08:44

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene

Published on: August 22, 2017

7.8K

科学领域:

  • 太阳能光伏和可再生能源
  • 材料科学 材料科学 材料科学
  • 有机电子 有机电子

背景情况:

  • 单片裂变 (SF) 将一个光子转化为两个高能三重激子,这一过程对于提高太阳能电池效率至关重要.
  • 了解薄膜微观结构,温度和SF效率之间的联系对于优化太阳能转换至关重要.
  • 由于其高效率,人类二氧化 (diF-TES-ADT) 衍生物是SF的有希望的材料.

研究的目的:

  • 在diF-TES-ADT薄膜中调查局部薄膜形态和初级单片裂变 (PSF) 效率之间的相关性.
  • 阐明晶度和温度在微观水平上对PSF效率的作用.
  • 通过考虑空间不均性,提供对优化SF材料的见解.

主要方法:

  • 低温光显微镜被用来空间解决PSF的效率.
  • 超光谱显微镜提供了亚微米分辨率的吸收和发射特性.
  • 用温度和时间分辨率的光谱学来分析刺激子的动态.

主要成果:

  • 在diF-TES-ADT膜中,发现PSF效率在空间上不均.
  • 较高的PSF效率与局部结晶度增加的区域直接相关.
  • 结晶区域中增强的PSF被归因于电荷转移 (CT) 状态的有利的内热对齐.

结论:

  • 局部膜形态,特别是结晶性,显著影响SF效率.
  • 为了准确的性能评估,必须考虑SF材料的空间不均性.
  • 仅依靠空间平均指标对太阳能应用中的SF材料评估可能会产生误导.