紫外线/硫酸盐与酸盐相结合,用于在氧化条件下去除化化合物:工艺变量的影响,转化产品和毒性
Roberta F Nunes1, Julio C O Ribeiro2, Valter H Carvalho-Silva2
1Research Group in Advanced Oxidation Processes (AdOx), Department of Chemical Engineering, Escola Politécnica, University of São Paulo, São Paulo, Brazil.
Environmental technology
|July 4, 2025
概括
这项研究优化了UVC/硫酸盐和UVC/硫酸盐+硫酸盐过程,以降解像2,4-DCP.这样的化. 结合的过程,特别是pH值8.5与60毫克L-1硫酸盐,显著提高了污染物的去除和减少毒性.
科学领域:
- 环境化学环境化学
- 先进的氧化过程 先进的氧化过程
- 水处理技术水处理技术
背景情况:
- 化是工业废水和地表水中发现的持久性有机污染物.
- 这些化合物由于其毒性和持久性,对水生生态系统构成重大风险.
- 有效的处理方法对于从水中去除这些反抗性污染物至关重要.
研究的目的:
- 用UVC/硫酸盐来确定2,4-二二 (2,4-DCP) 降解的最佳初始硫酸盐度和pH值.
- 评估UVC/硫酸盐作为基于硫酸盐 (PS) 的工艺预处理的有效性.
- 评估2,4-DCP和2,3,4,6-四化 (2,3,4,6-TeCP) 的降解以及副产品的毒性.
主要方法:
- 使用UVC/硫酸盐 (UVC/PS),UVC/硫酸盐和联合UVC/硫酸盐+PS工艺研究了2,4-DCP和2,3,4,6-TeCP的降解.
- 优化了紫外线/硫酸盐处理的初始硫酸盐度 ([SO3^2-]0) 和初始pH值 (pH0).
- 使用ECOSAR计划分析了转化产品和预测生态毒性.
主要成果:
- 2,4-DCP的最佳UVC/硫酸盐降解发生在[SO3^2-]0至60毫克L-1和pH0~8.5.5的温度下.
- 与单个工艺相比,联合的UVC/硫酸盐+PS工艺显著改善了去除2,4-DCP和2,3,4,6-TeCP的情况.
- 在UVC/硫酸盐+PS系统中,氧化占主导地位,导致处理水的毒性较低,正如ECOSAR所预测的那样.
结论:
- 紫外线/硫酸盐工艺,特别是作为预处理,有效地提高了化的降解.
- 在有氧条件下的联合UVC/硫酸盐+PS工艺为水处理提供了一个有前途的方法.
- 这种先进的氧化过程产生了较少的有毒副产品,减少了对水生生物的整体环境风险.
更多相关视频
相关概念视频
Oxidative Cleavage of Alkenes: Ozonolysis
11.2K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
11.2K
Oxidation of Alcohols
13.6K
In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, and their mechanism of action is provided.
The process of oxidation in a chemical reaction is observed in any of the three forms:
The process of oxidation in a chemical reaction is observed in any of the three forms:
13.6K
Preparation and Reactions of Thiols
6.7K
Thiols are prepared using the hydrosulfide anion as a nucleophile in a nucleophilic substitution reaction with alkyl halides. For instance, bromobutane reacts with sodium hydrosulfide to give butanethiol.
6.7K
Extraction: Advanced Methods
545
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
545
Electrophilic Aromatic Substitution: Sulfonation of Benzene
6.5K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
6.5K
Carboxylic Acids to Acid Chlorides
7.2K
Carboxylic acids react with SOCl2 or PCl5 to form acid chlorides. Amongst the carboxylic acid derivatives, acid chlorides are the most reactive and synthetically important derivatives. They are useful reagents for Friedel–Crafts acylation of some aromatic compounds.
7.2K


