对树脂复合材料中n-ZnO添加物的湿度学特征的影响
Abdulaziz Alayed1,2, Nikolaos Silikas1, David C Watts1,3
1Division of Dentistry, School of Medical Sciences, University of Manchester, Manchester, UK.
European journal of oral sciences
|July 4, 2025
概括
将纳米氧化 (n-ZnO) 添加到树脂复合材料中,降低了水吸附和溶解度,但增加了湿透膨胀和离子释放. 所有测试的n-ZnO度都符合ISO标准.
科学领域:
- 材料科学 材料科学 材料科学
- 生物材料工程 生物材料工程
- 聚合物化学 聚合物化学
背景情况:
- 基于树脂的复合材料是广泛使用的牙修复材料.
- 它们的性能可能会受到水的吸收的影响,导致降解.
- 纳米粒子的结合提供了一种修改复合材料特性的策略.
研究的目的:
- 评估不同纳米氧化 (n-ZnO) 度对模型树脂复合材料的湿透性能的影响.
- 为了评估水吸附,溶解度,湿透膨胀和离子释放.
- 为了确定n-ZnO添加是否会影响符合ISO 4049标准.
主要方法:
- 模拟树脂复合材料的配方包括Bis-GMA,TEGDMA,UDMA,玻璃,纳米颗粒和0-5重量%n-ZnO.
- 标本根据ISO 4049:2019准备并浸入水中168天.
- 测量了水吸附,溶解度和湿透膨胀;通过ICP-MS分析了离子释放.
主要成果:
- 增加n-ZnO度显著降低了水吸附和溶解度.
- 随着 n-ZnO 含量增加,湿度扩张的增加.
- 离子 (Zn2+) 的释放与n-ZnO度逐渐增加,达到675.1ppb的5重%.
结论:
- 纳米氧化的添加有效降低了树脂复合材料中的水吸附和可溶性.
- 然而,它会导致离子的释放和镜扩张的增加.
- 所有测试的配方均符合ISO 4049:2019对牙科材料的要求.
相关概念视频
Additives and Fillers in Concrete
135
Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...
The...
135
Moisture Content and Bulking of Aggregate
212
The moisture content of aggregates is a crucial factor in construction, particularly in concrete mixing, as it influences the total water required in the mix. Moisture content represents the water coated on the exterior surface of the aggregate existing in a saturated and surface-dry condition. The total water content of a moist aggregate is the sum of its moisture content and water absorption.
When aggregates are exposed to rain or sit in stockpiles, they absorb moisture, which must be...
When aggregates are exposed to rain or sit in stockpiles, they absorb moisture, which must be...
212
Effect of Sea Water on Concrete
473
Concrete exposed to seawater can undergo degradation like the dissolution of ettringite and gypsum, increasing the material's porosity and decreasing its strength. In contrast, the crystallization of salts within the concrete's pores can cause expansion, particularly above the waterline where evaporation occurs. Nonetheless, this expansion only happens when seawater, enabled by the concrete's permeability, manages to infiltrate the structure.
Concrete in areas between tide marks,...
Concrete in areas between tide marks,...
473
Accelerated Curing of Concrete
265
Accelerating concrete curing is achieved by applying heat and additional moisture. This process accelerates the hydration of the cement, resulting in an earlier strength gain in the concrete. Steam curing is a method wherein the concrete products are either transported through a chamber on a conveyor belt or encased in plastic, allowing steam at atmospheric pressure to circulate freely around them. This process begins with a phase of moist curing that typically lasts between 3 to 5 hours, after...
265
Superplasticizers
122
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
122
Waterproofing and Anti-Bacterial Admixtures in Concrete
113
Concrete's susceptibility to water absorption is due to the capillary action within the pores of its hydrated cement paste. This action draws water in, creating the need for waterproofing admixtures to prevent such penetration. The efficacy of these admixtures is contingent upon the water pressure, with variations arising from different conditions such as rain, capillary rise, or hydrostatic pressure in structures intended to hold water.
Waterproofing admixtures render concrete hydrophobic,...
Waterproofing admixtures render concrete hydrophobic,...
113


