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预先调节电流以激活反应部位,以便对长寿命金属阳极进行均剥离/合
Junhan Wu1,2, Chao Chen1,2, Junhao Zhang1,2
1National Engineering Research Center for Magnesium Alloys, National Innovation Center for Industry-Education Integration of Energy Storage Technology, College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China.
增加电流密度可以改善 (Mg) 阳极的均性,这与人们普遍认为的相反. 一个预先条件的当前策略可以提高Mg电池的性能和周期寿命.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- (Mg) 电池具有作为下一代能源存储的潜力.
- 金属阳极由于不均的剥离和涂层而表现出不良的循环寿命.
- 了解这种不均的起源对于改善Mg电池技术至关重要.
研究的目的:
- 在不同电流密度下系统地研究Mg阳极剥离/合行为.
- 探索含和无电解质对Mg阳极均性的影响.
- 确定提高Mg阳极电化学性能和循环寿命的策略.
主要方法:
- 在电流密度从0.5到5mA cm-2.2的Mg阳极剥离/涂层的系统研究.
- 在不同电流密度下分析Mg阳极电位分布.
- 在阳极表面处理中应用预条件电流 (PCC) 策略.
主要成果:
- 增加的电流密度 (0.5-5 mA cm-2) 增强了Mg阳极的形态统一性,挑战了化物腐蚀的作用.
- 较高的电流密度会导致电位分布均,从而促进同质的电化学反应.
- 该PCC策略显著提高了表面的均性,使稳定的Mg阳极循环在1mAcm-2.2时超过2500小时.
结论:
- 电流密度在Mg阳极表面行为中起着关键作用,较高的密度促进了统一性.
- 拟议的PCC策略有效地提高了Mg阳极表面的均性和电化学性能.
- 经过PCC处理的Mg阳极在Mg//Mo6S8全细胞中表现出极好的稳定性,在1000个周期内保持97%的容量.
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