鱼类石中的PFAS:对墨西哥加勒比海岸线的担忧日益增加
Biraj Saha1, Mohamed Ateia2, Sujan Fernando3
1Department of Civil, Construction and Environmental Engineering, North Dakota State University, Fargo, ND 58102, United States.
Journal of hazardous materials
|July 5, 2025
概括
在影响海岸线的藻中检测到和多基物质 (PFAS). 这些持久化学物质在海藻中积累,对其使用和处置构成挑战.
科学领域:
- 环境化学环境化学
- 海洋生物学 海洋生物学
- 污染研究 污染研究
背景情况:
- 自2011年以来,全球海底 Sargassum开花的加剧影响超过30个国家.
- 在全球范围内,石灰岩的开花带来了重大的环境和经济挑战.
- 在中存在的per-和多基物质 (PFAS) 的存在和影响在很大程度上仍未被调查.
研究的目的:
- 进行第一项关于藻中PFAS污染的调查.
- 分析来自墨西哥加勒比海的体中PFAS的类型和度.
- 了解 PFAS 在 Sargassum 中的分布和生物积累潜力.
主要方法:
- 在墨西哥加勒比海采集的石样本中分析了40种不同的PFAS化合物.
- 总PFAS度的量化和主要PFAS类别的识别 ( perfluorocarboxylic酸与 perfluorosulfonic酸).
- 评估PFAS在不同形态部分 (叶片,茎,膀) 的质量分布,并计算生物积累因子 (BAF).
主要成果:
- 检测到十个PFAS,总度为3.88±0.19 ng/g (干重).
- perfluorocarboxylic 酸 (80.7%) 在 perfluorosulfonic 酸 (19.3%) 上占主导地位,长链 PFAS (57.1%) 比短链更为普遍.
- PFAS质量因部分而异,脂质丰富的膀对长链PFAS有显著的贡献;Log BAF随着PFAS碳链长度的增加而增加.
结论:
- 气作为PFAS的载体,积累这些持久污染物.
- 这些发现复杂化了Sargassum的使用和处置,需要减少污染的策略.
- 估计每年PFAS装载量突出显示了墨西哥加勒比海和大西洋石灰带的问题规模.
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