在室温下,石墨烯中单个空隙和亚原子的移动性
Tuan T Tran1, Per O Å Persson2, Ngan Pham3
1Department of Physics and Astronomy, Ångström Laboratory, Uppsala University, Box 516, Uppsala, SE-751 20, Sweden.
Small (Weinheim an der Bergstrasse, Germany)
|July 7, 2025
概括
石墨烯空缺迁移长距离,造成全球应变,而表面污染物可以自我修复. 这项研究揭示了在离子辐射下缺陷移动性和晶格重建.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术纳米技术
背景情况:
- 离子辐射会导致石墨烯等材料的结构缺陷.
- 了解缺陷移动性对于材料稳定性和应用至关重要.
研究的目的:
- 在keV离子辐射下研究石墨烯中结构缺陷,和它们的组合的移动性.
- 为了阐明辐射石墨烯的应变效应和自我愈合机制.
主要方法:
- 自支持石墨烯的均且空间有限的keV Ar+离子辐射.
- 使用纳米孔面具来控制缺陷的产生.
- 使用选区电子衍射 (SAED) 和应变测量进行分析.
主要成果:
- 均的辐射诱导了拉伸力,随着缺陷密度的增加而减少,这表明应变放松.
- 空位表现出远程相互作用,影响全球格子应变.
- 单个空缺在室温高达100纳米的区域迁移到非辐射区域.
- 表面污染物通过阿达托姆诱导的晶格重建促进了自我愈合机制.
结论:
- 格子菌株促进空缺迁移,促进扩散到原始地区.
- 涉及阿达托姆的自我修复机制可以减轻由缺陷引起的退化.
- 石墨烯在辐射下的缺陷动态是复杂的,涉及到局部和远程效应.
相关概念视频
Network Covalent Solids
14.6K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
14.6K
First Law: Particles in Two-dimensional Equilibrium
5.2K
Recall that a particle in equilibrium is one for which the external forces are balanced. Static equilibrium involves objects at rest, and dynamic equilibrium involves objects in motion without acceleration; but it is important to remember that these conditions are relative. For instance, an object may be at rest when viewed from one frame of reference, but that same object would appear to be in motion when viewed by someone moving at a constant velocity.
Newton's first law tells us about...
Newton's first law tells us about...
5.2K
Fermi Level Dynamics
349
The vacuum level denotes the energy threshold required for an electron to escape from a material surface. It is usually positioned above the conduction band of a semiconductor and acts as a benchmark for comparing electron energies within various materials.
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
349
First Law: Particles in One-dimensional Equilibrium
7.1K
Newton's first law of motion states that a body at rest remains at rest, or if in motion, remains in motion at constant velocity, unless acted on by a net external force. It also states that there must be a cause for any change in velocity (a change in either magnitude or direction) to occur. This cause is a net external force. For example, consider what happens to an object sliding along a rough horizontal surface. The object quickly grinds to a halt, due to the net force of friction. If...
7.1K
Electron Configuration of Multielectron Atoms
54.8K
The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
54.8K
π Molecular Orbitals of 1,3-Butadiene
9.9K
Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
9.9K


