在不同反应系统中,在水处理前和后对青的表面功能组进行研究
Yudong Sun1, Zezhou Wang2, Ziyuan Liu1
1College of Chemistry & Chemical Engineering, China University of Petroleum(East China), Qingdao 266580, China.
水处理改变了青的表面功能组,减少了氧和酸,同时增加了酸. 即使在水处理后,基硫仍然占主导地位.
科学领域:
- 石油化学 石油化学
- 表面科学是一门学科.
- 催化剂是一种催化剂.
背景情况:
- 青是原油中发现的复杂的大分子.
- 了解它们的表面功能组对于精炼过程至关重要.
- 水处理是升级重石油分量的关键过程.
研究的目的:
- 在水处理之前和之后调查青的表面功能群的变化.
- 分析不同反应系统对青素成分的影响.
- 描述石中碳,氧,和硫的化学形式.
主要方法:
- 用X射线光电子光谱 (XPS) 来进行表面分析.
- 青是从Yumen大气残留物 (YMAR) 和Merey大气残留物 (MRAR) 中提取的.
- 在残留物和脱反应系统中进行了水处理.
主要成果:
- 青主要由碳,硫,和氧组成.
- 碳氧单键是占主导地位的氧气形式;氧氧在水处理后减少.
- 在水处理后,烯酸的含量增加,而烯酸的含量显著减少.
- 硫比硫硫更为丰富,这种趋势在水处理后仍然存在.
结论:
- 水处理显著改变了青的表面化学成分.
- 功能组的变化表明,水处理青的反应性和特性发生了变化.
- 在水处理过程中,XPS有效地阐明了结构变化.
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