活性化CO2捕获用于煤矿的回填材料 包含市政固体废物 焚烧底层灰
Guolan Dou1,2,3, Tian Zhang1,2,3, Gen Liu1,2,3
1Key Laboratory of Gas and Fire Control for Coal Mines, China University of Mining and Technology, Xuzhou 221116, China.
ACS omega
|July 7, 2025
概括
这项研究探讨了使用废物材料,如焚烧底灰 (MSWI-BA) 和废渣用于煤炭填充,捕获二氧化碳 (CO2). 这些绿色材料提供了低碳替代水泥,减少二氧化碳排放和减轻采矿风险.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 地质技术工程 地质技术工程
背景情况:
- 普通波特兰水泥 (OPC) 生产是全球二氧化碳排放的主要来源.
- 煤回填充为二氧化碳捕获提供了一个机会.
- 城市固体废物焚烧底灰 (MSWI-BA) 和颗粒高炉渣 (GBFS) 是潜在的补充水泥材料.
研究的目的:
- 调查使用含有MSWI-BA和GBFS的活性材料用于煤炭中二氧化碳捕获的可行性.
- 评估二氧化碳捕获对这些材料机械强度和微观结构的影响.
- 与OPC相比,评估这些新型填充材料的二氧化碳排放指数.
主要方法:
- 活性材料的制备有MSWI-BA和GBFS的不同比例.
- 碳化试验是在受控的湿度和二氧化碳度下进行的.
- 分析了二氧化碳吸收,压力强度,多孔性和微观结构变化 (XRD,SEM).
主要成果:
- 随着MSWI-BA含量增加,二氧化碳捕获能力增加,在40%的MSWI-BA中达到4.46%的重量.
- 碳化导致压力强度下降,但样品保持了结构完整性.
- 由于碳酸盐的形成,碳化后的多孔性显著下降 (高达22.2%).
- 微观结构分析证实碳酸盐生成增加,MSWI-BA纳入量更高.
- 二氧化碳排放指数至少比OPC.低51.9%.
结论:
- 结合MSWI-BA和GBFS的活性材料在煤炭回填充中显示出对二氧化碳捕获的希望.
- 这些材料提供了一个可持续的,低碳的替代传统的水泥基填充.
- 整合二氧化碳捕获和填充可以有助于降低大气中的二氧化碳度和减轻与采矿有关的灾害.
更多相关视频
相关概念视频
Pozzolans
202
Pozzolans are siliceous or aluminous materials blended with Portland cement. They interact with the calcium hydroxide produced during the hydration of Portland cement and contribute to improved strength and durability of concrete. The pozzolanic activity, a measure of a pozzolan's effectiveness, is typically assessed using the strength activity index, as defined in ASTM C 618-93, which calculates the ratio of the compressive strength of cement mixtures with and without pozzolan.
Fly ash is...
Fly ash is...
202
Additives and Fillers in Concrete
135
Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...
The...
135
Alkali Aggregate Reaction in Concrete
190
The alkali-aggregate reaction in concrete involves natural siliceous minerals in aggregates reacting with alkaline hydroxides derived from cement alkalis. This reaction forms an alkali-silica gel that absorbs water, swells, and increases in volume, which is confined by the surrounding cement paste, creating internal pressures that crack and disrupt the concrete. The extent of expansion and damage can be partly attributed to the alkali-silica reaction's osmotic hydraulic pressure and the...
190
Portland Cement
306
Portland cement is the essential binding ingredient in concrete, made from finely ground materials including lime, iron, silica, and alumina. Lime is derived primarily from limestone, marble, marl, seashells, and clays, which also supply iron and alumina, while silica is sourced from sand, chalk, and bauxite. Contemporary manufacturing of Portland cement is a significant source of carbon dioxide emissions, prompting research into reducing its content in concrete through alternative...
306
Sample Preparation for Analysis: Advanced Techniques
459
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
459
Bioremediation
20.2K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
20.2K


